咪唑根碱性离子液体在水介质Knoevenagel反应中的催化作用-催化学报.PDF

2011 Chinese Journal of Catalysis Vol. 32 No. 4 文章编号: 0253-9837(2011)04-0693-06 DOI : 10.3724/SP.J.1088.2011.01238 研究论文: 693~698 咪唑根碱性离子液体在水介质 Knoevenagel 反应中的催化作用 * 陈学伟, 宋红兵, 李雪辉 , 王芙蓉, 钱 宇 华南理工大学化学与化工学院, 制浆造纸工程国家重点实验室, 广东广州 510640 摘要: 报道了咪唑根 1-丁基-3- 甲基咪唑 ([Bmim]Im) 碱性离子液体的合成与表征, 该离子液体具有强碱性和较好的热稳定性. 碱 性离子液体[Bmim]Im 用于催化水介质中 Knoevenagel 反应, 发挥了碱催化剂与相转移催化剂双重作用. 此外, 离子液体 [Bmim]Im 及其水溶液还具有良好的循环使用性能. 水介质、低催化剂用量、室温与高收率、简单的后处理操作是该催化体系 的主要特点. 关键词: 咪唑根; 碱性; 离子液体; 水介质; Knoevenagel 反应 中图分类号: O643 文献标识码: A 收稿日期: 2010-12-26. 接受日期: 2011-02-16. *通讯联系人. Tel/Fax: (020 E-mail: cexhli@ 基金来源: 国家自然科学基金 . Catalytic Performance of Imidazolide Basic Ionic Liquid in Knoevenagel Reactions in Aqueous Media * CHEN Xuewei, SONG Hongbing, LI Xuehui , WANG Furong, QIAN Yu State Key Laboratory of Pulp Paper Engineering, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China Abstract: The synthesis and characterization of the basic ionic liquid, 1-butyl-3-methylimidazolium imidazolide ([Bmim]Im), were reported intensively. [Bmim]Im has strong basicity and relatively good thermal stability, and it was used as a novel catalyst for the Knoevenagel reactions in aqueous media. [Bmim]Im acted as both a base catalyst and a phase transfer catalyst in the Knoevenagel reaction. In addition, [Bmim]Im together with aqueous media had good recycle ability. Aqueous media, low catalyst concentration, simple separation workup,