碱式碳酸钴非等温热分解动力学-中南大学学报.PDFVIP

42 2 () Vol.42 No.2 2011 2 Journal of Central South University (Science and Technology) Feb. 2011 1,2 1,2 1,2 1,2 1,2 1,2 (1. , 650093 2. 650093) X (Coats-Redfern Achar )(Kissinger Flynn–Wall–Ozawa ) 2 2 ( 303 K 493 K 625 K ) 29.5%E 106.139~144.537 kJ/mollg A (A ) 9.396~11.868 O642 O643 A 1672−7207(2011)02−0356−05 Non-isothermal kinetics of thermal decomposition of basic cobalt carbonate LIU Bing-guo1,2, PENG Jin-hui1,2, ZHANG Li-bo1,2, ZHANG Ze-biao1,2, GUO Sheng-hui1,2, ZHANG Shi-min1,2 (1. Faculty of Materials and Metallurgical Engineering, Kunming University of Science and Technology, Kunming 650093, China; 2. Key Laboratory of Unconventional Metallurgy, Ministry of Education, University of Science and Technology, Kunming 650093, China) Abstracts: Kinetics and thermal decomposition behavior of basic cobalt carbonate was investigated using TG and XRD at various heating rates. Kinetic parameters of decomposition of basic cobalt carbonate for the second-stage was calculated and analyzed using model-fitting (Coats-Redfern method and Achar method) and model-free (Kissinger method and Flynn-Wall-Ozawa method). The results show that the decomposition process of basic cobalt carbonate is divided into two stages: the crystallization water begins to dehydrate at 303 K, decomposition of basic cobalt carbonate follows at 493 K and changes into Co O powder decomposition completely above 625 K in air atmosphere. The mass 3 4 loss of decomposition of ba