《新型苯并菲类盘状液晶化合物合成研究》-毕业论文.docVIP

w 摘 要 本论文的目的是合成一种新型苯并菲类盘状液晶化合物。试验方法如下：（1）以邻甲氧基苯酚为原料，与溴代正戊烷通过烷基化反应,合成了1-甲氧基-2-戊氧基苯；（2）之后， 1-甲氧基-2-戊氧基苯与一氯化碘反应，使1-甲氧基-2-戊氧基苯在对位发生碘代，得到对位1-甲氧基-2-戊氧基碘代苯；（3）1-甲氧基-2-戊氧基碘代苯在铜粉作用下，260℃通过Ullmann偶联反应生成3,3’-二甲氧基-4,4’-二戊氧基联苯；（4）3,3’-二甲氧基-4,4’-二戊氧基联苯与邻苯二戊醚发生氧化并环反应，合成3,6-二甲氧基-2,7,10,11-四戊氧基苯并菲。所合成的化合物的化学结构通过红外和核磁的手段进行了确认，最终目标化合物的液晶性能采用偏光显微镜和示差量热仪进行了表征。 关键词：苯并菲 盘状液晶 ABSTRACT The purpose of this paper is to synthesize a new type of discotic liquid crystal triphenylene.The steps are as follows,(1)1-methoxy-2-pentyloxy benzene was synthesized by methylpyrocatechine and bromo pentane through Alkylation;(2)1-methoxy-2-pentyloxybenzene was iodinated by iodine monochloride and the iodine atom substitute the hydrogen atom in contraposition with the 1- methoxy;(3)3,3-dimethoxy-4,4–dipentyloxy diphenyl was synthesized through Ullmann Coupling reaction with the catalysis of copper under 260°C;(4)the target compound ,3,6-dimethoxy-2,7,10,11-tetrakis (pentyloxy) triphenylene ,was synthesized through the oxidation of 3,3-dimethoxy-4,4–dipentyloxy diphenyl and 1,2-bis(pentyloxy)benzene;The chemical structures of compounds were identified by using spectroscopy (IR),nuclear magnetic resonance (1HNMR). Key words: triphenylene discotic liquid crystal PAGE w 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc288404263 第一章 绪论 PAGEREF _Toc288404263 \h 4 HYPERLINK \l _Toc288404264 1、液晶的概述 PAGEREF _Toc288404264 \h 4 HYPERLINK \l _Toc288404265 2、盘状液晶概述 PAGEREF _Toc288404265 \h 4 HYPERLINK \l _Toc288404266 3、苯并菲类盘状液晶概述 PAGEREF _Toc288404266 \h 5 HYPERLINK \l _Toc288404267 4、课题研究内容意义 PAGEREF _Toc288404267 \h 7 HYPERLINK \l _Toc288404268 第二章 实验部分 PAGEREF _Toc288404268 \h 8 HYPERLINK \l _Toc288404269 2.1 主要试剂 PAGEREF _Toc288404269 \h 8 HYPERLINK \l _Toc288404270 2.2.实验仪器 PAGEREF _Toc288404270 \h 8 HYPERLINK \l _Toc288404271 2.3.反应原理 PAGEREF _Toc288404271 \h 9 HYPERLINK \l _Toc288404272 2.4.合成方法 PAGEREF _Toc288404272 \h 10 HYPERLINK \l _Toc288404273 2.4.1 1-甲氧基-2-戊氧基苯的合成 PAGEREF _Toc288