《新型氨基磺酸盐高效减水剂的合成、复配及应用研究》》-毕业论文.docVIP

PAGE 精品 精品 郑州大学毕业设计（论文） 题 目：新型氨基磺酸盐高效减水剂的合成、复配及应用研究 Study on Synthesis, Composite and Application of New-type Amino Sulphonic Acid-Based Superplasticizer 指导教师： 职称： 研究员 学生姓名： 学号： 专 业： 高分子材料专业 院（系）： 材料科学与工程 完成时间： 年 月 日 摘要 目前广泛使用的萘系高效减水剂由于在低水灰比下的混凝土流动性小、坍落度损失较大使得它在泵送混凝土和高性能混凝土中的应用受到很大限制。氨基磺酸系高效减水剂具有对水泥粒子的高度分散性，减水率高，混凝土的耐久性好，并具有控制坍落度损失的功能，是很有发展前途的一种新型高效减水剂。 本文详细介绍了氨基磺酸盐高效减水剂的分子结构及性能特点，国内外氨基磺酸盐高效减水剂的研究及应用现状，并且从作用机理入手探讨了氨基磺酸盐高效减水剂的合成方法及发展趋势。 本文以对氨基苯磺酸钠、苯酚、尿素与甲醛为主要原料合成氨基磺酸系高效减水剂AF。根据分子设计的原则，通过改变原料单体摩尔比、溶液浓度、温度等工艺参数，进行了氨基磺酸系高效减水剂的合成试验。结果表明对氨基苯磺酸钠与苯酚的摩尔比为1:1.3、(对氨基苯磺酸钠+苯酚):甲醛为1:1.2，合成的氨基磺酸系高效减水剂AF陛能最好。 同时对氨基磺酸盐减水剂和萘系减水剂复配研究，研究表明两者复配具有良好的效果，净浆流动度有着明显的提高，同时在复配过程中复配效果和减水剂对水泥适应性有较大关联。 关键词：氨基磺酸盐高效减水剂，合成，复配，减水机理 Abstract Now naphthalin series water-reducing agents were widely used as superplasticizers. However，the low water-cement ratio concrete having low mobility and large slump loss were critial defects. These faults limited its use in pumping concrete and high-performance concrete. Amino sulfonate superplasticizers have high degree of dispersion of cement particles. They also have high water reduction rate. What is more, concrete can gain good durability and the slump loss can be controlled. So, Amino sulfonate superplasticizers are considered as a new promising and efficient water-reducing agent. This paper described the molecular structure of the amino sulfonate superplasticizer and the characteristics of its performance in details. We also introduced the current situation of research and application of Amino sulfonate superplasticizers in domestic and overseas. Besides,we will discuss the synthesis methods and developing trends of the amino sulfonate superplasticizers on the base of the reaction mechanisms. In this paper，we synthesized the amino sulfonate superplasticizer AF using p-amino benzene sulfonate, phen