I型和II型结构气体水合物的记忆效应.PDFVIP

物理化学学报(Wuli Huaxue Xuebao) June Acta Phys. -Chim. Sin . 2011, 27 (6), 1305-1311 1305 [Article] I 型和II 型结构气体水合物的记忆效应 刘 瑜 赵佳飞 郭长松 宋永臣* 刘卫国 程传晓 叶陈诚 薛铠华 (大连理工大学教育部海洋能源利用与节能重点实验室, 辽宁大连116023) 摘要: 利用水合物二次生成实验装置, 采用“定容法”对I 型( 甲烷、二氧化碳)和II 型(丙烷)结构气体水合物的二 次生成进行了实验, 研究了不同结构水合物(I 型、II 型)彼此间的记忆效应, 发现水合物生成过程存在明显的诱 导期, I 型结构水合物间在二次生成过程中存在着记忆效应. I 型与II 型结构水合物之间在相互二次生成过程中 存在着显著的记忆效应. 关键词: 诱导时间; 二次生成; 记忆效应; 多孔介质; 气体水合物 中图分类号: O642 Memory Effects of Structure I and II Gas Hydrates LIU Yu ZHAO Jia-Fei GUO Chang-Song SONG Yong-Chen* LIU Wei-Guo CHENG Chuan-Xiao YE Chen-Cheng XUE Kai-Hua (Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, Dalian University of Technology, Dalian 116023, Liaoning Province, P. R. China) Abstract: We studied the reformation processes for structure I (sI) (methane, carbon dioxide) and structure II (sII) (propane) gas hydrates experimentally and investigated the memory effects between sI and sII hydrates using a constant-volume system. During these experiments, the induction period for hydrate formation was observed. Moreover, we also found that there were obvious memory effects in secondary formation of sI gas hydrates as well as in alternate secondary formation of sI and sII gas hydrates. Key Words: Induction time; Reformation; Memory effect; Porous media; Gas hydrate 1 引 言