矾土基耐火可塑料结合剂优化研究及仿真模拟-材料科学与工程专业论文.docx

万方数据 万方数据 Abstract Plastic refractory which has the ability of flexibility and repair to damage parts is one of unshaped refractory. The most widely used plastic refractory is alumina plastic with high refractoriness, thermal shock resistance and abrasion resistance. There are many experiments about the property of alumina plastic, but little study focused on the reaction mechanism and erosion mechanism. Investigating the discrepancy of property with different binding agents, this work explored the reaction mechanism and the influence of high temperature liquid phase, with simulation of the service condition in metallurgical furnace at the end. With phosphoric acid as binding agent, experiments tested the particle size distribution of raw material firstly. Sintered with diverse binding agents at 110℃, 850℃ and 1350℃, the samples were compared for the study of difference of property. With the analyses of X-ray diffraction and scanning electron microscopy, the mechanism of different strength was investigated. Using the parameters of high-temperature thermodynamics, the distribution of stress simulated by COMSOL Multiphysics in the working furnace could be revealed. By the analysis of physical properties, the optimum particle size gradation was 1-3mm : ≤1mm : ≤0.074mm = 47 : 18 : 25. Dried at 110℃, the samples bound with phosphoric acid had a batter strength than others. As import of Na+ ion, the samples with sodium hexametaphosphate and sodium metasilicate, which generated liquid phase at sintering process, making samples densification as glass phase, had a batter room temperature property than the samples with phosphate. The samples with Na+ ion added generated liquid phase form 1150℃, and then the liquid phase began to erode mullite from one side, which finally inundated and resolved the particle of mullite with the temperature increasing. The mass liquid phase affected the high-temperature behavior of samples seriously. At 1400℃, the samples