磁性超滤膜分离多糖的分析-农产品加工与贮藏专业论文.docxVIP

PAGE PAGE IV Abstract Abstract In recent years, the polysaccharide is becoming a new research hot spot. Ultrafiltration is one of the most widely used technology of membrane separation, which was used for separating polysaccharides well since its excellent separation efficiency, no phase transition and harmless to the biological activity. In this paper, polysulfone(Psf)–Fe3O4 composite ultrafiltration membrane which was invented by Hefei University of Technology was applied to separate polysaccharides for the first time. The efficiency and principle of the magnetic ultrafiltration membrane was discussed, and the structure of MEP was also analyzed. The main contents of the papers were as follows： The Psf-Fe3O4 composite ultrafiltration membrane was made by phase -inversion process, and the polymer dope was consisted of Psf(15%),DMF(83%) and PEG(2%),and nano-sized Fe3O4 particles was added (2g/100mL)whose size was 20nm. The magnetic membranes attribute indicated: Its interception molecular weight was about 20 000Da. The addition of nano-sized Fe3O4 particles caused the porosity of Psf-Fe3O4 magnetic compound membrane to be bigger than the common Psf membrane, and also caused the rigidity enhanced. The SEM micrographs showed that Fe3O4 particles distributed well in the membrane, the cross section of magnetic membrane was typical sponginess structure. The ultrafiltration of diamagentic material——Dextran showed that the rejection was influenced by the deformation of membrane pore in the magnetic field. Its principle may be: ①Fe3O4 nanoparticles had magnetic striction, the change of the dimensional size of Fe3O4 nanoparticles may bring deformation of the skin layer and pore structure. ②The Fe3O4 nanoparticles distributed in the membrane would twist for trying to arrange along the magnetic line of force and caused deformation of the skin layer and pore structure. ③ Two styles, sediment and pack particle existed in the composite ultrafiltrati