臭氧工艺去除难降解有机物调控方法分析-环境科学与工程专业论文.docxVIP

哈尔 哈尔滨工业大学工学硕士学位论文 - - II - Abstract It becomes a hot topic that to remove refractory micro-pollutants in drinking water. Ozonation is widely used for the treatment of drinking water for degradation of organic compands. But in the practical application of the ozone process, there’s no basis for evaluation of refractory organics removal effect and regulation of ozone dosage. The purpose of this paper is to study a methematic model of the representative organic nitrobenzene ozonation base on Instantaneous Ozone Demand (IOD), ozone exposure (CT) which are used to characterize the two phase of ozonation respectively and regulation methods of ozonation process base on this model. A tube reactor (TR) for ozonation was designed to measure the dissolved ozone concentration from the starting 2.2s after ozone addition. By using this reactor we obtained variation law of the IOD and CT: the ozone dosage, pH, DOC, alkalinity are positively correlated with the IOD; in addition to ozone dosage, the CT is negative related with the other three factors. Due to ozonation process is divided into two stages, the integral nitrobenzene removal rate of ozonation process was equal to the sum of the removal rate in two ° ° ° phases, η=η1+η2=η1+?η1+η2 . η1 ( η1=a1×IOD+b1 ) and η2 ( η2=a2×CT+b2 ) are the removal rates in the first and second phase, respectively, while ?η1 represents the variation caused by changes of water quality.The model for the nitrobenzene oxidation by ozone in the testing water quality is shown as follows: η=η1+η2=40.43× IOD+?η1+12.4×CT+8.2. The similar model for other water quality can be obtained as the same method adopted in this paper. Based the ozone oxidation nitrobenzene model, three methods to improve the performance of nitrobenzene ozonation been obtained: increasing ozone dosage, reducing DOC or alkalinity in raw water.Based on the conclusion that reduce DOC concentration can raise nitrobenzene removal rate in ozone process, we try to use two pretreat