超细非晶体二氧化硅与工业搪瓷釉复合及其工程化应用研究-材料工程专业论文.docxVIP

摘要 摘要 万方数据 万方数据 瓷釉复合工业搪瓷制成的工业搪瓷反应釜在染料行业已经获得应用，大幅度 延长了该设备的使用寿命，应用情况良好。 关键词： 工业搪瓷，超细非晶体二氧化硅，耐酸性，耐热急变性， 显微结构 II Abstract Abstract ULTRAFINE AMORPHOUS SILICA AND INDUSTRIAL ENAMEL COMPOUND AND ITS ENGINEERING APPLICATION RESEARCH ABSTRACT In this thesis, the industrial enamel frit formula had been designed and the industrial enamel frit was prepared. The industrial enamel mill addition formula had been designed and the industrial enamel slips were developed. On this basis, the physical and chemical properties of industrial enamel had been tested and the influence of different mill additions on the industrial enamel had been analyzed. The structure of industrial enamel with different mill additions has been characterized, and the reason of ultrafine amorphous silica for improving the thermal shock resistance performance of industrial enamel has been analyzed. The research results show that the thermal stability of industrial enamel can be greatly enhanced and the acid alkali resistance of industrial enamel has little effect by the ultrafine amorphous silica as mill addition. With the increase of mill addition ratio, the thermal stability increasing of industrial enamel tends to stop, and the smoothness and gloss of porcelain enamel surface have been declined. In order to achieve good general properties of industrial enamel, it is appropriate for adding about 9wt% ultrafine amorphous silica into industrial enamel. From the microscopic analysis, with the increase of ultrafine amorphous silica, more III white spots on the porcelain surface can be found by electron microscopy. The ultrafine amorphous silica appears to accumulate. In addition, with the help of X-ray polycrystalline diffraction analysis and Fourier transform infrared imaging microscope analysis, it can be discovered that the amorphous silica, which is added into industrial enamel, will still be an amorphous state after firing process. In order to further study the effect of ultrafine amorphous silica a