《年产3万吨丁苯橡胶装置聚合工段工艺设计》-毕业论文设计.doc

年产3万吨丁苯橡胶装置聚合工段工艺设计 化工与材料工程学院毕业设计 - PAGE 50 - - PAGE I - 摘　　要 本设计为年产3万吨乳液聚合丁苯橡胶装置工艺设计，以聚合工段为设计的主要对象。丁二烯和苯乙烯为主要聚合单体，松香酸钾皂、硫酸亚铁、叔十二碳硫醇、过氧化氢对锰烷等为助剂，采用低温乳液聚合法连续生产工艺合成丁苯橡胶。丁苯橡胶具有优异的物理性能和良好的加工性能，在工业生产和日常生活中应用广泛。本设计在掌握丁苯橡胶合成原理、聚合方法、工艺流程以及国内外的发展现状的基础上，进行了聚合工段的物料衡算、热量衡算、主要设备选型计算及简单的技术经济分析，以及绘制带控制点的工艺流程图、设备布置图、管道布置图，编写了设计说明书和设计计算书。 关键词：丁苯橡胶；乳液聚合；工艺设计；丁二烯；苯乙烯 Abstract This design for the annual output of 30000 tons of emulsion polymerization of styrene butadiene rubber plant process design based on polymerization section design of the main object. Butadiene and styrene as the main monomer, rosin potassium soap, ferrous sulfate, uncle twelve carbon mercaptan and hydrogen peroxide as additives on manganese alkanes, etc, the continuous production process using emulsion polymerization at low temperature synthesis of styrene-butadiene rubber. Styrene butadiene rubber has excellent physical properties and good processability, has been widely applied in industrial production and daily life. This design in mastery of styrene-butadiene rubber synthesis principle, polymerization method, technological process and the development situation at home and abroad, on the basis of the aggregation process of material balance, heat balance and major equipment selection calculation and simple technical and economic analysis, and draw the control points of process flow diagram, equipment layout, piping layout, writing the design specification and design calculation. Key Words：Butadiene-styrene rubber；Emulsion polymerization；Process design；Butadiene；Styrene 化工与材料工程学院毕业设计 目　　录 TOC \o 1-4 \h \u HYPERLINK \l _Toc29309 摘　　要 PAGEREF _Toc29309 I HYPERLINK \l _Toc21366 Abstract PAGEREF _Toc21366 II HYPERLINK \l _Toc6029 第一篇 设计说明书 PAGEREF _Toc6029 1 HYPERLINK \l _Toc29110 2. 绪 论 PAGEREF _Toc29110 2 HYPERLINK \l _Toc7581 2.1. 设计依据、指导思想 PAGEREF _Toc7581 2 HYPERLINK \l _Toc8630 2.1.1. 设计依据 PAGEREF _Toc8630 2 HYPERLINK \l _Toc6451 2.1.2. 指导思想 PAGEREF _Toc6451 2 HYPERLINK \l _Toc5585 2.2. 设计