纺织品中烷基酚聚氧乙烯醚检测方法研究-纺织工程(染整)专业论文.docx

纺织品中烷基酚聚氧乙烯醚检测方法研究 纺织品中烷基酚聚氧乙烯醚检测方法研究 II II 以甲醇和二氯甲烷的混合溶剂（体积比甲醇：二氯甲烷=2：3）为萃 取溶剂，萃取时间 20min，萃取温度 35℃，超声功率 350W。HPLC/MS 的最佳分析条件为：Zorbax SB C18 为色谱柱，甲醇-10mmol/L 乙酸 铵为流动相，烷基酚聚氧乙烯醚定量母离子形式选择[M+NH4]+型， 辛基酚单聚氧乙烯醚和壬基酚单聚氧乙烯醚的毛细管传输电压分别 设定在 80eV 和 70eV 为最佳。 本文研究的测试方法的方法检测限为 0.02-1.03mg/kg，回收率在 93-106%之间，相对标准偏差(RSD)均小于 6.27%。经过与现有标准相 比，本课题研究的测试方法具有检测效率高，所需时间短，误差小， 前处理试剂用量少，能检测出低聚合度烷基酚聚氧乙烯醚的优点。该 测试方法能够满足实际检测的需要。 关键词：烷基酚聚氧乙烯醚；低聚合度；高效液相质谱联用法； 超声波萃取；检测 PAGE PAGE IV RESERCH ON THE METHOD OF DETECTION ALKYLPHENOL ETHOXYLATES IN TEXTILES ABSTRACT Alkylphenol ethoxylates (APEO),as a kind of polyoxyethylene nonionic surfactants, widely exist in textile auxiliaries which were often used in chemical processing of textile products when dyeing and finishing. The commercial alkylphenol ethoxylates were mainly nonylphenol ethoxylates (NPEO) and octylphenol ethoxylates (OPEO). APEO are stable and degrade slowly in the environment.When they are gathered，theywill show the toxicity.The degradation products of APEO are nonylphenol (NP), octylphenol (OP), and short chain NP1EO, NP2EO and NP3EO,which will be kept for a longer time in the environment and show greater toxicity.Some of them have a kind of environmental hormone properties which can disrupt wildlife and humans’s endocrine function.So alkylphenol ethoxylates had been prohibited or restricted by many countries and organizations. The present methods of detecting alkylphenol ethoxylates in textiles have disadvanages in detecting the components of APEO with different polymerization degree,and even more can’t detect APEO with low polymerization degree. So the present methods can’t meet the demands for Oeko-tex? standard 100-2012.In addition, soxhlet extraction need long time,so it difficult to meet the needs of the mass detection. The study established afast,efficient and comprehensive approach that can detectlow degree alkylphenol ethoxylates in textiles. Firstly APEO were extracted from textiles by ultrasonic extraction technology.Then