臭氧氧化去除水中残杀威的实验研究城市水资源专业论文.docxVIP

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 - - PAGE IV - - - III - Abstract Propoxur, a carbamate insecticide, is one of the public health pesticides recommended by the World Health Organization. It has been widely used in disease prevention in 2008 after the Wenchuan earthquake, resulting in a high propoxur residue in environment. Because of its high water solubility, propoxur is easy to transport in environment, then access to the surface and ground water and threaten drinking water safety. In order to eliminate propoxur micro-pollution and to ensure the safety of drinking water, technologies on the removal of propoxur micro-contamination are studied in this paper. First, potassium permanganate, chlorine, ozone and powdered activated carbon on the ability of propoxur removal were investigated. The investigation shows that propoxur is not well removed by potassium permanganate, chlorine and powdered activated carbon, but by ozone. When T = 13 °C and pH = 6.5, ozone of the initial concentration of 0.65mg/L can completely remove the propoxur of the initial concentration of 200μg/L within 30min. Secondly, factors that influence the ozonation of propoxur were studied. The results show that increasing the initial ozone dosage conduce to the rapid removal of propoxur; pH affect the ozonation process of propoxur significantly, under acidic conditions the rate of the degradation of propoxur is relatively slow, while under alkaline conditions the removal rate of propoxur is fast; the radical inhibitor tert-butyl alcohol can significantly slow the degradation rate of propoxur, the greater tert-butyl alcohol dosage the more obvious inhibition on the degradation rate. when the dosage of tert-butyl alcohol increased to certain value, the inhibitory effect of tert-butyl alcohol is no longer enhanced; the chloride, sulfate and nitrate ions in aquatic environment do not affect the degradation of propoxur by ozone, while bicarbonate alkalinity inhibits the pro