《孔型对5052铝合金阳极氧化膜耐蚀性能的影响》-毕业论文（设计）.doc

摘要 铝合金阳极氧化膜在较强的腐蚀环境中，仍可能发生氧化膜的局部孔蚀，降低其使用寿命。针对膜孔孔型对铝合金阳极氧化膜耐蚀性能的影响，实验通过改变阳极氧化工艺参数电流密度和硫酸浓度制备具有不同显微形貌的阳极氧化膜试样；使用NSⅢa3多功能扫描探针显微镜观察不同氧化膜试样的显微形貌，得到氧化膜孔型的大小形状，膜孔的分布规律及膜孔边缘的峰强起伏变化；对生成的氧化膜进行厚度、显微硬度和耐蚀性能的测试，得到氧化膜试样的抗腐蚀性能。对比分析氧化膜孔型显微形貌对铝合金阳极氧化膜厚度、硬度和耐蚀性的影响。 随硫酸浓度和电流密度的改变，阳极氧化膜的显微形貌结构发生变化。在硫酸浓度和电流密度较低时，氧化膜表面膜层呈壁垒型分布，膜孔排列无序，孔径大小不均匀，膜孔密度低，氧化膜经封孔处理后的力学和电化学性能较低；随电流密度和硫酸浓度的升高，氧化膜表面以多孔层膜堆积，膜孔排列规则呈蜂窝状，孔径大小和孔高均匀，孔密度高，整个氧化膜表面较平整，封孔处理后获得高的力学和电化学性能氧化膜；过高的电流密度和硫酸浓度则会加快氧化膜的溶解，导致氧化膜松软，孔隙率增大，氧化膜表面粗糙和局部缺陷，其力学和耐蚀性能下降。 关键词：5052铝合金；阳极氧化；氧化膜孔型；耐蚀性 Abstract When the anode oxidation film of the aluminum alloy staying in strong corrosive environment, the local corrosion still happens, leading to the reduction of its life. According to the effection of corrosion resistance of the anode oxidation film in aluminum alloy, the experiment intends to make anodic oxidation films with different microscopic morphology through changing the anodic oxidation process parameters which include current density and the concentration of sulphuric acid.Observe the microscopic morphology of different simples by using atomic force microscope, receive the data which including the size of the caliber in the oxidation film, the distribution of the caliber and the fluctuation of the edge of the caliber.Testing the thickness, microhardness and the corrosion resistance of the oxide film, and get conclusion of the corrosion resistance of the oxidation film.Comparing and analysing the effection of the microstructures of the oxide film on the tickness, hardness and the corrosion resistance of the anode oxidation film in the aluminum alloy. With the sulphuric acid concentration and current density change, anodic oxidation film of microscopic morphology structure changes. When sulphuric acid concentration and current density is lower, oxidation film surface membrane layer type distribution, the barriers of film hole arrangement disorder, pore size uniform, film hole density low, the mechanics and electrochemical performance i