分光光度法测量海洋沉积物的碘跟量新.pdfVIP

Advances in Analytical Chemistry 分析化学进展, 2016, 6(2), 35-42 Published Online May 2016 in Hans. /journal/aac /10.12677/aac.2016.62006 The Measurement of Iodine in Marine Sediments Using Spectrophotometric Method Lihong Ji, Guangshan Liu College of the Environment and Ecology, Xiamen University, Xiamen Fujian th nd th Received: May. 4 , 2016; accepted: May. 22 , 2016; published: May. 27 , 2016 Copyright © 2016 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Abstract Spectrophotometric method of measuring iodine in marine sediment has been established in this paper. We have studied the iodine in marine sediment cores collected from East Pacific, East China Sea, Jiaozhou Bay, and coastal sea areas of Fujian. For marine sediment sample, iodine was leached with water from sample after it was treated by mixing it with KOH and combusted. Under the acid addition, the iodide in leachant was oxidized into iodate by adding saturated bromine solution. IO3− reacted with I− to form I2 after starch-KI mixing solution, as the color reagent, was added with excess I−. The measurement was performed by ultraviolet and visible spectrophotometer. It has been shown when igniting sample, the ratio range of 1:3 to 1:5 for sediment to KOH and keeping the combusting temperature at 500˚C- 800˚Cfor 1 - 4 h are suitable. The most absorbance of light is at wavelength of 580 nm. For the sediment sample of iodine content in the range of 2 - 100 mg/ kg, when the 2 g of sample was treated, 6 - 12 drops of mixing solution of the 20 g/dm3 starch and 3