等离子渗镀TiN工艺及性能的研究-材料加工工程专业论文.docx

摘 要 摘 要 等离子 等离子渗镀 TiN 工艺及性能的研究 - - PAGE III - 万方数据 - - IV - 万方数据 St udy on Pr ocess and Pr oper t i es of Ti N synt hesi zed by Pl asma Per meat i ng Techni que Abst r act As a new type of ceramic material, TiN is very suitable for surface coated material on cutting tools, moulds and bearings for its excellent properties, such as low density, high hardness, good conductivity, good wear resistance, oxidation resistance property, high corrosion resistance and so on . Therefore, the preparation of TiN hard coating has been getting more attention by researchers. Using double glow plasma surface alloying technique, titanizing was conducted on the surface of Q235 steel and tens of microns titanium solid solution diffusion layer formed. Later nitrogen gas was blown to synthesis TiN permeation layer directly. The microstructure, component concentration, hardness and phase analysis of TiN permeation layers were tested. The optimum technological parameters of titanizing and synthesis stage were obtained. The variation laws of phase structure, surface morphology, composition, appearance and micro-hardness of TiN permeation layer were achieved. The wear resistance tests for TiN permeation layer, untreated Q235 steel, quenched +tempered T10 steel and nitrided 3Cr13 steel were carried out under the same conditions. The electro-chemical corrosion tests for TiN permeation layer, 1Crl8Ni9Ti stainless steel and untreated Q235 steel in l mol/L H2SO4 solution，3.5% NaCl solution and 4% NaOH solution were carried out . The results showed that: TiN permeation layer could be formed on the surface of Q235 steels by the double glow plasma surface alloying technology. The optimum technological parameters were as follows: The parameters of titanizing Stage included: Ultimate vacuum 1～3Pa, working gas Ar, working pressure 25～35 Pa, source voltage –1000V, sample voltage –600V, holding temperature 1050℃, holding time 2h. The parameters of synthesis Stage included: