改性煤矸石TiO2复合材料的制备及其光催化性能的研究-高分子化学与物理专业论文.docx

中北大学学位论文 中北大学学位论文 万方数据 万方数据 TiO2 的降解率高 33.18%。 以 AgNO3 为原料，NaOH 为沉淀剂，K2S2O8 为氧化剂，采用液相沉淀法将 AgO 与 溶胶凝胶法在最佳条件下制得的 TiO2/HAG 复合，制备得到 TiO2/HAG/AgO 催化杀菌复 合材料。利用 SEM、TEM 和 XRD 对 TiO2/HAG/AgO 复合光催化材料进行了表征。以 罗丹明 B 模拟废水评价复合材料在紫外光下的光催化活性。结果表明：AgO 的质量比 越大，其复合材料的光催化活性越低。并通过抑菌圈法测试复合材料的杀菌性能，当 TiO2/HAG 与 AgO 的质量比为 1:3 时，其杀菌性能最佳。 以 HAG 为载体， SrFe12O19 为 磁 核 ， 采 用 溶 胶 - 凝 胶 法 负 载 TiO2 制得 TiO2/SrFe12O19/HAG 磁载光催化复合材料。利用 SEM、TEM、XRD 和 VSM 对磁载光催 化材料的表面形貌、晶体结构和磁性能进行了表征。以罗丹明 B 模拟废水评价复合材料 在紫外光下的光催化活性。结果表明：随着 SrFe12O19 质量分数的增加磁载光催化材料 的光催化活性先升高后降低，当 SrFe12O19 的质量分数为 35%，光催化活性最大，较 TiO2/45HAG 的催化活性高，并且能够实现磁回收利用。 关键词：改性煤矸石，二氧化钛，光催化性能，抑菌性，磁性 Preparation and photocatalytic performance of modified gangue/TiO2 composite Abstract It is difficult to separate TiO2 from the already purified water due to the small particle size, which causes the low reuse rate. Therefore, the load of TiO2 nanomaterials on the carrier could not only overcome the disadvantage of the low reuse rate, but also improve the photocatalytic activity of the composite photocatalyst utilizing the adsorption quality of porous adsorption material carrier. The carriers of TiO2 could be divided into organic and inorganic carriers. Inorganic carriers have advantages of high chemical stability, high temperature and pressure endurance. Among them porous adsorption materials have a good adsorption peformance, which mainly include activated carbon, carbon nanotubes and fly ash and so on. It is difficult to expand production because activated carbon and carbon nanotubes are costly. Therefore, the modified coal gangues were used as carriers to composite with TiO2. The modified coal gangue could be used as adsorption carrier because of its large specific surface area and could achieve the utilization of coal gangue as resource which once was industrial waste.The specific research methods and contents are shown as follows: Firstly, the coal gangue was modified using hydrochloric acid (HAG, short for hydrochloric a