复合式固定化细胞生物反应器处理氰化物的研究-环境工程专业论文.docx

II II 通气有气相氰挥发。在复合反应器中，对于高浓度氰化物也有良好降 解效果，当进口氰浓度为高达450 mg/L和650 mg/L时水力停留时间为 24 h时去除率能达到98%以上，且排出气体中未检出氰化物。以200 mg/L氰液为进口废水，进行复合反应器的连续运行，去除率基本维 持在95%至98%。运行45天后氰去除率仍能达到90%以上。当进水氰 浓度提高至627 mg/L，此时仍达到92.3%的去除率，说明该复合反应 器可耐一定的负荷冲击。 关键词：氰化物 玉米芯 吸附 固定化 复合式生物反应器 III III A HYBRID IMMOBILIZED CELLS BIOREACTOR FOR THE TREATMENT OF CYANIDE ABSTRACT Cyanide is deadly toxic, but it is widely used in industrial production because of the strong complexing of CN-, thus produces large amounts of cyanide wastewater. Cyanide is very easily to form hydrogen cyanide under neutral and acidic conditions, hydrogen cyanide is highly volatile for its boiling point is only 26℃. Therefore air pollution control in the process of cyanide wastewater treatment is very important. The aim of the present study was to build a hybrid immobilized cell bioreactor, to investigate the feasibility of simultaneous removal of liquid and gaseous cyanide, and offer new method for biological treatment of cyanide contamination. Natural material corncob was selected as immobilization carrier according to previous research in our group, and its properties of cyanide adsorption were investigated here. The result showed that the increasing of cyanide adsorption rate slowed down after 2 hours, and the final adsorption rate at 7 h was 29.27%. After autoclaved at 121℃ for 20 min, it took longer to get adsorption equilibrium. However, the final a adsorption rate were nearly the same. Cyanide adsorption rate of the PAGE PAGE VI corncobs increased with the increasing of its dosage, but the amount of CN- adsorbed on unit weight of corncobs tended to be closed. The higher the initial cyanide concentration was the greater the amount of adsorbed cyanide was under the same condition. The effect of pH (8, 9, 10) on the adsorption process were studied, it was found that alkali environment promote the cyanide adsorption, the final adsorption rate for pH8, 9, 10 after 8 h were 29.6%, 43.8% and 56.1% respect