低品位菱锰矿提制活性四氧化三锰和二氧化锰的工艺优化-安全技术及工程专业论文.docx

重庆大学 重庆大学硕士学位论文 英文摘要 PAGE PAGE VI ABSTRACT With the rapid development of industry, the demand of manganese resources was growing. There was a trend toward full utilization of low-grade rhodochrosite ore (LGRO), owning to their abundant reserves and low price. Mn3O4 and MnO2 were important metal oxides and widely used in the electronic industry, the chemical industry, environmental protection, and so on. In this study, MnSO4 solution, which was obtained by leaching and purifying of LGRO, was used as raw material of Mn3O4 and MnO2 preparation. The preparation procedures were studied and promoted. This research was of great significance to provide a possible high efficiency way for the utilization of LGRO. Mn3O4 was prepared by two-phase oxidation method, and the preparation procedures were studied and promoted. The results showed that the Mn3O4 with high purity and high specific surface area could be obtained under the following processes. The MnSO4 solution of 1.0 mol/L was added into beaker under a flow rate of 30mL/h. The pH of the reaction solution was adjusted to 10 using NH3·H2O at 80?C. Then the solids were washed and dried at 200?C for 2.5 h. The total Mn content (TMC) of Mn3O4 was 72.0 %, which was larger than that of the premium grade of mangano-manganic oxide for preparing soft magnetic ferrites. The ionic distributions was formulated as [Mn2+][Mn2+0.3024Mn3+ Mn4+ □ ] O . The average 0.2937 0.3786 0.0254 2 4 crystallite size of Mn3O4 with tetragonal hausmannite structure was about 35 nm by XRD analysis. BET specific surface area of the Mn3O4 reached to 31.8m2/g. High-purity Mn3O4 was prepared by decomposing MnCO3, and the effects of decomposition time and temperature on the TMC were studied. The Mn recovery efficiency was more than 97 % with the blended precipitant of Na2CO3 and NH4HCO3 (1:1mol/mol). The TMC of product increased with increase of decomposition time and temperature. The quantitative relationship between TMC and decomposi