沸石负载TiO2-CdS复合半导体的制备及光催化制氢研究-化学工程与技术专业论文.docx

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 - - II - Abstract The photocatalytic production of H2 is a combinative technology of environmental treatment and cyclic utilization of resource. The key technology mainly focuses on the development of catalysts with strong visible light response, high photo-catalytic efficiency and the long lifetime. In view of the disadvantages of easy condensation, low HYPERLINK /dict_result.aspx?searchword=%e9%87%8f%e5%ad%90%e4%ba%a7%e7%8e%87amp;tjType=sentenceamp;styleamp;t=quantum%2Byield quantum yield, low HYPERLINK /dict_result.aspx?searchword=%e5%88%a9%e7%94%a8%e7%8e%87amp;tjType=sentenceamp;styleamp;t=utilization utilization of light in TiO2 power, and easy photo-corrosion in bulk CdS , We used sol-gel method to prepare zeolite loaded TiO2 photocatalyst, prepare zeolite-loaded CdS by ion exchange and precipitation method, and combining these two methods to prepare zeolite loaded TiO2-CdS photocatalyst. The effects of the preparation conditions, such as calcination temperature, ratio of sol and zeolite and exchange times were investigated. The structure and physicochemical properties were characterized by UV-Vis diffuse reflection spectra, XRD, FT-IR, ICP-AES and SEM-EDS. The performance of photocatalytic production of H2 over the above photocatalysts under high pressure mercury lamp and xenon lamp were also studied. It was known from the characteristic results that zeolite loaded TiO2 was better when calcined at 400℃, the ratio zeolite and sol was 1g zeolite / 5ml sol, in which TiO2 was anatase, and the introduction of TiO2 changed the surface morphology of zeolite. In the zeolite loaded CdS system, CdS was hexagonal structure, a blue shift of the adsorption edge in UV-Vis diffuse reflection spectra by HYPERLINK /dict_result.aspx?searchword=%e9%87%8f%e5%ad%90%e5%b0%ba%e5%af%b8%e6%95%88%e5%ba%94amp;tjType=sentenceamp;styleamp;t=quantum%2Bsize%2Beffect quantum size effect, and exchange times was two best. A red shift of the adsorption edge