浮岛型人工湿地无机浮体材料的制备-材料学专业论文.docxVIP

ABSTRACT Artificial floating island is an ecology landscape started in recent years. It has a significant role in purification and remediation of polluted water. Silicate glass have many superior performances such as high chemical resistance, tailored porosities, high strength, no secondary pollution. It is the preferred material used in artificial floating island. In this paper, Borosilicate foam glasses were prepared by sintering powder. We find out the basic formula and the best firing system through the investigation of the kind of foaming agent , the amount of foaming agent and foam stabilizer. The effects of additives(Sb2O3,CaSO4,Ba(NO3)2) on borosilicate foam glass have also been investigated. X-ray diffraction (XRD) were used to analyze the crystalline phase and scanning electron microscope (SEM) were used to characterize pore structure. The bulk density ， porosity, compressive strength and thermal expansion coefficient were also tested. Results indicated that: when the additive amount of foaming agent carbon was 1%, the pore size was more homogeneous and the shape was spherical. Under this additive amount, the bulk density, porosity and the compressive strength was 0.346g/cm3, 83.53%, and 3.24MPa. When the graphite was foaming agent, the bulk density was larger than that made of carbon. What’s more, the foam glass was difficult to machine. When the additive amount of foam stabilizer was 4wt.%, the borosilicate foam glasses presented uniform pores structure and the average pore size was 0.5mm. The best firing temperature was 775℃ after adding foam stabilizer and the bulk density was 0.434g/cm3, compressive strength was 3.18MPa and the porosity was 79.33%. When added Sb2O3 in the batch, the shape of pores had a little variation looking like ellipse. The bulk density decreased firstly and then increased. The change rule of thermal expansion coefficient was as same as that of bulk density. The compressive strength increased with the addition of Sb2O3. W