RET复配SBR改性沥青流变特性及机理分析.pdfVIP

第42卷 第11期 北 京 工 业 大 学 学 报 Vol.42 No.11 2016年 11月 JOURNAL OF BEIJING UNIVERSITY OFTECHNOLOGY Nov. 2016 RET复配SBR 改性沥青流变特性及机理分析 陈治君,郝培文 (长安大学公路学院,西安摇 710064) 摘摇 要:为了解决沥青路面使用性能要求越来越高的问题,提出采用反应型聚合物沥青改性剂(reactive elastomeric terpolymer,RET)复配丁苯橡胶(styrene鄄butadiene rubber,SBR)的方案来获得综合性能优越且性价比较高的改性沥 青. 通过多应力蠕变恢复(MSCR)试验、小梁弯曲(BBR)试验、原子力显微镜和傅里叶红外光谱试验对不同RET掺 量与SBR复配改性沥青的流变特性及其微观改性机理进行了研究. 结果表明:掺加适量的RET后,RET、SBR和基 质沥青相互发生化学交联反应,复合改性沥青中形成新的大分子物质和化学交联网络结构,显著提高了复合改性 沥青的高温稳定性、低温抗裂性及其稳定性,可有效延缓沥青路面早期破坏的发生. 关键词:反应型聚合物沥青改性剂(RET);丁苯橡胶(SBR);复合改性沥青;流变性能;改性机理 中图分类号:U414 文献标志码:A 文章编号:0254-0037(2016)11-1691-06 doi:10.11936/ bjutxb2016020012 Rheological Characteristics of RET Compound SBR Modified Asphalt and Its Mechanism Analysis CHEN Zhijun,HAO Peiwen (College of Highway,Chang爷an University,Xi爷an710064,China) Abstract:In order to solve the problem of the increasingly high requirement of asphalt pavement performance,a solution of reactive elastomericterpolymer (RET)compounding styrene鄄butadienerubber (SBR) was proposed to obtain modified asphalt with superior comprehensive and cost鄄effective performance. In this paper, the rheological properties and micro modification mechanism of different content of RET compound SBR modified asphalt binders were studied through MSCR test, BBR test, atomic force microscope and Fourier infrared spectrum experiment. The test results show that RET,SBR and baseasphalthaveinteractivechemicalreactionsandformanew macromoleculematerialandchemical interactive network structure in compound modified asphalt, which significantly improves high temperature stability,crack resi