均相沉淀法制备Ce018Y012O119氧化物固溶体的-常州大学学报.PDF

第20 卷第2 期 江 苏 工 业 学 院 学 报 Vol1 20 No1 2 2008 年6 月 JOURNAL OF JIANGSU POLYTECHNIC UNIVERSITY Jun1 2008 : 1673- 620 (2008) 02- 0001- 05 * Ce01 8Y01 2 O11 , , ( , 213164) : Ce ( NO ) # 6H OY ( NO ) # 6H O , pH Ce3+ Y3+ 3 3 2 3 3 2 pH : pH , pH x = 0~ 351 5 ( x : ) , pH x , x , x = 0 10Lm x = 351 5 015 Lm500 e , 1 h , X- Y CeO , 2 12 nm : ; ; Ce01 8Y012 O11 : O 614132 : A Study of Preparing Ce01 8Y01 2 O11 Solid Solution by Homogenous Precipitation YANG Chun- juan, DONG Ru- lin, CHEN Zhi- dong ( School of Chemistry and Chemical Engineering, Jiangsu Polytechnic University, Changzhou 213164, China) Abstract: Oxalate solid solution w as obtained in a mixed aqueous solution system of diethyl oxalate, cer-i um nitrate and yttrium nitrate w ith urea as pH adjuster by homogenous precipitation. It w as found that the pH of the mixed solution system decreased w ith increasing temperature because of increased hydrolysis of 3+ 3+ the diethyl oxalate and Ce , Y ion. The hydrolysis of the urea not only promoted the hydrolysis of the diethyl oxalate but also increased the pH of the mixed solution. Both the pH values before heating and at the precipitation increased w ith increasing x (x : mole ratio of urea to diethyl oxalate ) w hen the x