壳聚糖介质金纳米盘的可控合成及生长机理ControllableSynthesisof.PDF

2012 年第 70 卷 化 学 学 报 Vol. 70, 2012 第 3 期, 259～264 ACTA CHIMICA SINICA No. 3, 259～264 ·研究论文· 壳聚糖介质金纳米盘的可控合成及生长机理 杨传孝 孙向英* 刘 斌 (华侨大学材料科学与工程学院 厦门 361021) 摘要 水浴加热氯金酸、壳聚糖和纳米金种子的混合液, 以壳聚糖为稳定剂和还原剂成功合成了表面等离子体共振 (SPR)吸收峰位可调的金纳米盘. SEM 电镜图像表明纳米金盘主要为三角形和截角三角形, 其边长在 170 nm 左右. X 射 线衍射分析表明金纳米盘是以{111}面为盘状面的高纯金单晶. 讨论了金纳米盘的生长机理. 在最佳条件下金纳米盘的 面内偶极等离子共振吸收峰位于 920 nm. 实验结果表明通过控制壳聚糖的量、金种子的加入量、水浴温度及水浴时间 可以有效地控制近红外等离子吸收峰位及吸收强度. 关键词 金纳米盘; 壳聚糖; 表面等离子体共振吸收 Controllable Synthesis of Chitosan-Mediated Gold Nanoplate and the Growth Mechanisms Yang, Chuanxiao Sun, Xiangying* Liu, Bin (College of Materials Science and Engineering, Huaqiao University, Xiamen 361021) Abstract By chitosan as a stabilizer and reducing agent, the tunable surface plasmon resonance (SPR) ab- sorption peak of gold nanoplate has been successfully fabricated by water bath heating of solution containing HAuCl4, chitosan and gold nanoseeds. The SEM images indicated that the gold nanoplates were mainly composed of triangular and truncated triangular shape. The edge is about 170 nm. X-ray diffraction analyses indicated that the gold nameplates were pure single crystals with {111} planes as their basal planes. The growth mechanisms on synthesis of chitosan-mediated gold nanoplate were discussed. Under optimum con- ditions the SPR absorption peak of gold nanoplate in-plane dipolar is 920 nm. The experiment results showed that the near-infrared SPR