梳形结构的侧链密度对聚羧酸系减水剂性能的影响-硅酸盐学报.PDF

1570 2012 40 11 Vol. 40 No. 11 2 0 1 2 1 1 JOURNAL OF THE CHINESE CERAMIC SOCIETY November 2012 ( 100124) : (PCA)PCA 50 2.5 1 PCA PCA 25% TU528 A 0454–5648(2012)11–1570–06 2012–10–31 10:54:55 /kcms/detail/11.2310.TQ1054.201211.1570_006.html Effect of Side Chain Density of Comb-shaped Structure on Performance of Polycarboxylate Superplasticizer WANG ZimingLU Zichen LU Fang LI Huiqun (College of Materials Science and Engineer, Beijing University of Technology, Beijing 100124, China) Abstract: A serial of polycarboxylate superplasticizers (PCA) with the same main chain length and gradually decreased side chain density were synthesized via the design of the polymer structure and the optimization of the synthesis technology based on the reac- tion theory of free radical polymerization. In addition, their molecular mass, molecular mass distribution and the conversion ratio were measured by gel permeation chromatograph. The results reveal that the polymerization rate is low when the acid to ether ratio is : less than 2.5 1 for the macromonomer with a polymerization degree of 50. In order to investigate the effect of the PCA structures on the performance, the cement paste fluidity experiments were conducted with three different adding methods, i.e., conventional mass adding method, same amount of effective PCA adding method and equimolar PCA adding method, respectively. The results show that the initial fluidit