添加氧化铈对AZ91D镁合金表面富镁涂层的保护作用-物理化学学报.PDF

物理化学学报(Wuli Huaxue Xuebao) February Acta Phys. -Chim. Sin . 2012, 28 (2), 407-413 407 [Article] doi: 10.3866/PKU.WHXB201112164 添加氧化铈对AZ91D 镁合金表面富镁涂层的保护作用 * 王雅萍 赵旭辉 卢向雨 左 禹 (北京化工大学材料科学与工程学院, 北京100029) 摘要: 通过Machu 测试、电化学交流阻抗(EIS)和扫描电子显微镜(SEM)等方法研究了添加氧化铈对AZ91D 镁合金表面富镁涂层防护性能的影响. 氧化铈添加量较少(0.1%, w)时, 对涂层耐蚀性无影响; 添加量过多(3%) 时, 涂层耐蚀性降低; 添加氧化铈颗粒为0.5%时, 涂层的阻抗增大, 涂层电容降低, 对AZ91D 镁合金基体的保 护性能明显提高. 尽管添加氧化铈不改变富镁涂层对AZ91D 镁合金的保护机制, 但可显著延长涂层的服役寿 命. 氧化铈能够降低纯镁颗粒的电化学反应活性, 使镁粉腐蚀速率降低, 阴极保护时间延长. 添加一定量氧化铈 后, 也有利于涂层屏蔽性能提高, 氧化铈能降低AZ91D 镁合金表面阳极腐蚀电流密度, 提高镁合金腐蚀电位, 从而有利于富镁涂层发挥对镁合金基体的阴极保护作用. 关键词: 耐蚀性; AZ91D镁合金; 富镁涂层; 氧化铈; 电化学交流阻抗 中图分类号: O646 Corrosion Protection of Ceria Particles in Mg-Rich Primer on AZ91D Magnesium Alloy WANG Ya-Ping ZHAO Xu-Hui LU Xiang-Yu ZUO Yu* (School of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China) Abstract: The effect of ceria particles on the corrosion resistance of Mg-rich primer on AZ91D magnesium alloy was studied using the Machu test, electrochemical impedance spectroscopy (EIS), and scanning electron microscopy (SEM). The results show that addition of a small amount of cerium oxide (0.1% , mass fraction) had no effect on the corrosion resistance of the coating, and the addition of excessive particles (3%) reduces the corrosion resistance of the coating. However, addition of 0.5% ceria particles t