合肥市郊水稻土中重金属的吸附淋溶特性研究-矿物学、岩石学、矿床学专业论文.docxVIP

Study Study on Adsorption and Leaching Properties of Paddy-Soil Heavy Metal in Suburb of Hefei City Abstract As an important way for increasing yield in agricultural production,fertilization also c锄accelerate remediation of contaminated soil by heavy metal．It has been showed that Phosphorous fertilizers can alter soil surface charge by acid radical， which influence metal ions sorption by soil． In this paper,paddy·soil heavy metal in Daxing and Yicheng which are the suburb of Hefei City has been taken as main researching objects，the transport characteristics of heavy metals in soil，the influencing factors and their effecting mechanisms we∞studied by comprehensive methods such as static isotherm adsorption experiment．Batch equilibration method was used in this experiment Adsorption thermodynamics and isotherm of heavy metals in two typical soils weae studied． Adsorption thermodynamics was carried out on adsorption properties and mechanisms of heavy mentals onto paddy-soil．The isothermal heavy metals absorption data obtained all fitted with：Langmuir and Freundlich equation．．The results show that adsorption data ofthree heavy mentals onto two types)fpaddy-soil fitted well to the Langmuir and Freundlich isotherms．The negative of adsorption Gibbs free enegy changes in all the cases are indicative of the spontaneous nature，which show chemical sorption coexist with physical sorption and the values of adsorption entropy changes are positive． The effective factors on absorption of heavy metals in paddy-soil were also studied．The results showed that temperature and phosphate have effect on the absorption of heavy metals．The absorption quantity increased with phosphate．With temperature increasing，the Cd、Pb absorption increased．With temperature inc北asing， the Hg absorption decreased． To obtain the knowledge of the impact on the environmem risks of acid rain and phosphate，all investigation Was undertaken．As one part of the research，soil column experiments were conducted to under