1,8-萘酰亚胺类荧光化合物合成研究的.doc

成绩 本科毕业论文 题目：1,8-萘酰亚胺类荧光化合物的合成研究 学生姓名 学 号 指导教师 院 系 专 业 年 级 教务处制诚信声明 本人郑重声明：本人所呈交的毕业论文（设计），是在导师的指导下独立进行研究所取得的成果。毕业论文（设计）中凡引用他人已经发表或未发表的成果、数据、观点等，均已明确注明出处。除文中已经注明引用的内容外，不包含任何其他个人或集体已经发表或在网上发表的论文。 特此声明。 论文作者签名： 日 期： 年 月 日摘 要 本文主要研究荧光染料在汽车空调系统荧光检漏中的应用，寻找或合成出可以应用于汽车空调系统荧光检漏的荧光染料。通过阅读大量文献，自行设计合成出适合的荧光染料。本实验以4-溴-1,8-萘酐为原料经过亚胺化4-溴-N-十烷基-1,8-萘酰亚胺得到了的反应条件即4-溴-1,8-萘酐和十胺一次性加料，，60℃水浴加热至回流，降温至50℃反应h，静置过夜取代反应4-溴-N-十烷基-1,8-萘酰亚胺0℃水浴加热，4-烷氧基-N-十烷基-1,8-萘酰亚胺化合物～50nm之间均有明显的发射峰；其中以正丁醇和乙二醇丁醚为原料合成得到的物质荧光强度很强。 关键词：荧光检漏 4-溴-1,8-萘酐4-溴-N-十烷基-1,8-萘酰亚胺4-烷氧基-N-十烷基-1,8-萘酰亚胺 Abstract In this research, the study of fluorescent dyes is in the automotive air-conditioning system in the application of fluorescence leak detection.It is searchor synthetize fluorescent dyes which can be applied to fluorescent leak detection inthe vehicles air-conditioning system. By way of reading amount of documents,synthesize suitable fluorescent dyes by myself.The study synthesize the intermediate product 4-bromo-N-dodecylamine-1,8-naphthalimide used 4-bromo-1,8-napht-halenedianhydride as raw materials through the imidization reaction. Yielding and marigining of melting point as indicators optimized the imidizationprocess,that was 4-bromo-1,8-naphthalene dianhydride Without purified and octadecyla-mine were onetime fed and their ingredi-ent ratio was 1:1.1. The reaction temperature was heated to 60 ℃ then cooled down t-o 50 ℃. Thereactiontime was 4h. The reactiondeposit overnight then filtrated it. The yield of the intermediate product 4-bromine-N-dodecylamine-1,8-naphthalimide was up to 82.6%. The study synthesize yellow or orange goal products 4-alkoxy-N-dodecyl-amin-e-1,8-naphthalimide through the substitution reaction which used product last step and alcohols as raw materials in alkaline conditions and the existence of surfactant. Th-e conditions of synthesis was 80 ℃ waterba