对乙酰氨基酚修饰的后交联树脂对双酚A的吸附性能.PDFVIP

中国环境科学 2010,30(6) ：775~779 China Environmental Science 对乙酰氨基酚修饰的后交联树脂对双酚 A 的吸附性能 肖谷清 1,2*,龙立平 1,王姣亮 1,徐满才 2 (1.湖南城市学院化学与环境工程系,湖南 益阳 413000 ；2.湖南师范大 学化学化工学院,湖南 长沙 410081) 摘要：用二氯乙烷为溶剂,用 FeCl3 为催化剂,使氯球和对乙酰氨基酚发生 Friedel-Crafts 反应制得了对乙酰氨基酚修饰的后交联树脂,对其 结构进行了表征,研究乙酰氨基和酚羟基二类氢键作用位点修饰的后交联树脂对双酚 A 的吸附性能.结果表明,红外光谱显示对乙酰氨基酚 已被成功地修饰在后交联树脂上.对乙酰氨基酚修饰的后交联树脂与氯球相比,BET 比表面积、孔容明显增大,孔径明显变小.对乙酰氨基酚 修饰的后交联树脂对双酚 A 的吸附量明显高于 75%活性炭的聚砜微球对双酚 A 的吸附量.对乙酰氨基酚修饰的后交联树脂对双酚 A 的吸 附为放热、自发的过程;树脂可以用 100%酒精解吸,解吸率为 99.92%;吸附动力学数据符合一级吸附速率方程,颗粒内扩散是吸附速率的主 要控制步骤,吸附速率同时还受液膜扩散的影响. 关键词：对乙酰氨基酚；后交联树脂；双酚 A ；吸附热力学；吸附动力学 中图分类号：X703 文献标识码：A 文章编号：1000-6923(2010)06-0775-05 Adsorption performances for bisphenol A onto the hypercrosslinked resin modified by acetaminophen. XIAO 1,2* 1 1 2 Gu-qing , LONG Li-ping , WANG Jiao-liang , XU Man-cai (1.College of Chemistry and Environmental Engineering, Hunan City University, Yiyang 413000, China ；2.College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China). China Environmental Science, 2010,30(6)：775~779 Abstract ：The adsorption performances for bisphenol A onto the hypercrosslinked resin with two kinds of the hydrogen bond site of acetamino group and hydroxyl group was studied. The hypercrosslinked resin modified with acetaminophen was synthesized with chloromethylated polystyrene and acetaminophen by Friedel-Crafts reaction. Dichloroethane was used as solvent and ferric chloride was used as catalyst. The structures of the hypercrosslinked resin were characterized. The acetaminophen was successfully modified into the hypercrosslinked resin that revealed by the Infrared spectra. Comparison with the chloromethylated polystyrene, the BET surfac