冠醚功能化聚偏氟乙烯微球的制备及其锂同位素分离性能.PDFVIP

第 36 卷 第 5 期 辐射研究与辐射工艺学报 J. Radiat. Res. Radiat. Process. Vol.36, No.5 2018 年 10 月 /fushe/CN/volumn/home.shtml October 20 18 冠醚功能化聚偏氟乙烯微球的制备及其 锂同位素分离性能 张雅婷 敖银勇 刘雪梅 赵 岩 宋宏涛 刘 波 黄 玮 （中国工程物理研究院核物理与化学研究所 绵阳 621900 ） 摘要 通过预辐射乳液接枝法制备了一种以聚偏氟乙烯(Polyvinylidene difluoride, PVDF)为载体，固载苯并 15 冠 5 (B15C5)螯合剂的功能微球。利用傅里叶红外光谱分析、元素分析、扫描电镜等手段表征微球的结构形 貌，并研究其对锂同位素的吸附分离性能。结果表明：功能化后微球上冠醚的固载量可达 1.2 mmol/g，微球 对锂离子的吸附平衡时间为 20 h ；微球对阴离子软度较高的锂盐具有更好的吸附效果：在常温、中性溶液中 对硫氰酸锂中 Li+ 的吸附容量最高，约为4.50 mg/g ；微球对醋酸锂的同位素分离因子可达 1.05±0.02。 关键词 苯并 15 冠 5，锂同位素分离，预辐射乳液接枝，固液萃取 中图分类号 TL13 DOI: 10.11889/j.1000-3436.2018.rrj.36.050303 Preparation and characterization of polyvinylidene difluoride microsphere grafted by benzo-15-crown-5 for lithium isotope separation ZHANG Yating AO Yinyong LIU Xuemei ZHAO Yan SONG Hongtao LIU Bo HUANG Wei (Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900, China) ABSTRACT Polyvinylidene difluoride (PVDF) microspheres functionalized with aminobenzo-15-crown-5 (PGB5) were prepared via pre-irradiation emulsion grafting polymerization of glycidyl methacrylate. The chemical structure and performance in lithium isotope separation of the PGB5 microspheres were characterized by Fourier-transform infrared (FT-IR) spectroscopy, elemental analysis, and scanning electron microscopy (SEM). The loading capacity of + aminobenzo-15-crown-5 was ~1.2 mmol/g. The e