环己烷脱氢膜反应器中复合膜的研究-化学工程专业论文.docxVIP

Abstract Study ofthe composite membrane used in the membrane reactor of dehydrogenation of cyclohexane TKs paper mainly studied the composite membrane used in the membrane reactor of dehydrogenation of cyclohexane，to make a fotmdational research in the application ofH2． A1203 SOl was made by the ultrasonic method and the common method respectively．The SOl made by the ultrasonic method Was more stable than the SOl made by the comlnon method．and by the effect of the ultrasonie． the ternperature of hydrolyzation was 10wer and the time of making SOl was shorter．It shows that the ultrasonic method is all eriective method of making AIOOH s01．At the same time．the optimum condition of making S01 was determined and Can be described as follows：the proportion between the aluminum iso．propoxide and H20 was l：6吐1：200 and the olle between the aluminum iso—propoxide and HN03 was 1：O．07～1：0．20； the temperature ofhydrolyzation was 65℃． The unsupported and supposed A1203 membrane were made by sol-gel method respectively．The specific surface area of A1203 membrane was 115．63m2／g and the mean pore size was 1．5-3nm．Knusen diflusion was occurred in the membrane and the separation factor of H2／N2 and H2／02 was 3．25 and 3．75． Carbon molecular sieve membrane(CMSM)was made by pyrolysis method and was coated on the A1203 membrane．The specific surface area of CMSM Was 465．68 l 3m2／g and the mean pore size Was 0．9um．The separation factor of H2，N2 and H2／02 was 7．07 and 5：47，respectively， larger than the theoretical value of Knusen diffusion，and Can be explained by the molecular sieving mechanism． Key words：A1203 gel，sol—gel method，A1203 membrane，pyrolysis method，carbon molecular sieve membrane  石油大学(华东)硕士论文 第1章前言 随着全球经济的飞速发展，对能源的需求也与日俱增。据统计， 目前全球有大约63％的能源来源于石油和天然气Il J。然而，由于石油 和天然气属于不可再生资源，大量的消耗使得本已紧张的世界石油市 场的竞争日趋激烈，更由此而引发了一系列的复杂问题；同时，由于 大量的石油、天然气以及煤炭等化石燃料的应用，全球环境也随之恶 化，环境保护问题也日益成为人们关注的焦点。因此，寻找一种可再 生、高效率、无污染的清洁能源成为目前许多国家研究的重点。 这其中，氢能作为一种储量大、可循环、无污染的能源H益引起 世界各国的重视，各国都投入大量的资金及人力物力进行氢能的研 究。我国也紧跟