《电解液成分对AZ91D镁合金微弧氧化膜层结构和耐蚀性的影响》-毕业设计论文（学术).docVIP

电解液成分对AZ91D镁合金微弧氧化膜层结构和耐蚀性的影响 Effect of electrolyte on the microstructure and corrosion resistance of coatings formed by micro-arc oxidation on AZ91D magnesium alloy 摘 要 微弧氧化是近年来兴起的一种新型的表面处理方法，其可以在金属表面原位生长出性能优良的陶瓷膜层。 本文以AZ91D镁合金为基体，在含有不同组分含量的电解液中制备出微弧氧化膜，利用扫描电镜观察了膜层的表面与截面微观形貌，通过超景深显微镜测量了膜层的厚度，采用全浸试验法分析了电解液中不同组分的含量对微孤氧化膜耐蚀性的影响。结果表明：陶瓷膜层大致有内部致密层和外部疏松层组成，致密层组织致密，和基体结合紧密；疏松层组织疏松，存在孔洞、裂纹等缺陷；随着电解液中硅酸钠含量的增加，膜层耐蚀性呈现先提高后降低的变化趋势，铝酸钠、四硼酸钠及氢氧化钠对膜层耐蚀性的影响与硅酸钠类似，当电解液中硅酸钠含量、铝酸钠含量、四硼酸钠含量以及氢氧化钠含量分别为15g/L、12g/L、3g/L以及2g/L时，膜层耐蚀性最好。 关键词：镁合金；微弧氧化；陶瓷膜；耐蚀性 PAGE \* MERGEFORMAT II Abstract Micro-arc oxidation is a new surface treatment technology by which a ceramic layer with good performance can be obtained on the metal surface. In this paper, ceramic coatings were prepared on AZ91D magnesium alloy by micro-arc oxidation. The surface morphology, cross section, film thickness and corrosion resistance of each of the coatings were characterized by scanning electron microscopy(SEM), super preview microscope and immersion test method. The results showed that coatings consisted of compact layer inside and lose layer outside. The compact layer combined with substrate tightly. Some hole and micro-crack existed in the lose layer. The corrosion resistance of the film increased at first and then decreased with the increase of the content of different anions, i.e., SiO32-, AlO2-, B4O74- and OH-. The ceramic film obtained in the electrolyte with 15g/L sodium silicate, 12g/L aluminum sodium, 3g/L sodium borate and 2g/L sodium hydroxide has the best corrosion resistance. Keywords: Magnesium alloy；Micro-arc oxidation；Ceramic film；Corrosion resistance PAGE \* MERGEFORMAT IV 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc295401798 第一章 绪 论 PAGEREF _Toc295401798 \h 1 HYPERLINK \l _Toc295401799 1.1引言 PAGEREF _Toc295401799 \h 1 HYPERLINK \l _Toc295401800 1.2镁及镁合金的特性、应用现状以及发展趋势 PAGEREF _Toc295401800 \h 2 HYPERLINK \l _Toc295401801 1.2.1镁及镁合金的特性 PAGEREF _Toc295401801 \h 2 HYPERLINK \l _Toc29540180