钢铁中钒、钛元素激光探针成分分析与检测-物理电子学专业论文.docxVIP

华 中 科 技 大 学 硕 士 学 位 论 文 II II Abstract Vanadium and titanium resources are important strategic resources in our country, and the comprehensive utilization of vanadium, titanium and associated minerals needs more and more rigid element detection technology. Traditional detection methods can not be satisfied with the requirements due to its complex procedures and long detection time. By taking advantage of the characteristics of fast, real-time and high-precision of laser probe, vanadium and titanium element analysis and detection in metal ore were presented in the dissertation. The optimal experimental parameters for vanadium and titanium element analysis and detection are explored through self-built laser probe system in this dissertation. The experimental results showed that, laser energy density of 10 ~ 30 J/cm2, and 1 ~ 6 μs of delay time are optimal parameters to obtain ideal spectroscopy intensity and signal/background(S/N) ratio, as well as the characteristic spectral lines and S/N ratio increased with laser wavelength shifting from infrared to ultraviolet. Using the optimized parameters, the limit of detection, 15 ppm for vanadium and 32 ppm for titanium can be obtained. The quantitative analysis of vanadium and titanium element based on basic scaling and internal calibration was also presented in this dissertation. According to the experimental results, the linear fitting of calibration curve for vanadium and titanium element can be reached to 0.995 and 0.992, and the relative error were 3.16% and 3.71% respectively which showed that the laser probe technology can be applied into the precision analysis of vanadium and titanium elements. Key words：Laser probe Laser-induced breakdown spectroscopy Plasma Vanadium and titanium elemental analysis and detection PAGE IV PAGE IV 目 录 摘 要 I Abstract II 1 绪论 1.1 引言 (1) 1.2 激光探针简介(1) 1.3 激光探针成分分析技术的优点及其应用 (2) 1.4 钒钛综合利用技术的发展以及国内外研究现状 (5) 1.5 本课题的来源、目的及意义 (8) 1.6 本文的主要内容 (8) 2 激光探针的实验装置及其研究方法 2.1 激光探针的主要设备简介