高固含量多元共聚无皂乳液的制备及其用于防水涂料的研究-精细与功能高分子材料专业论文.docxVIP

高固含量多元共聚无皂乳液的制备 高固含量多元共聚无皂乳液的制备 及其用于防水涂料的研究 摘 要 本文研究了HEA／st／BA多元体系的无皂乳液共聚反应，制备出固含量 达50％的稳定乳液。研究中发现，亲水性单体HEA不仅为乳胶粒子提供 亲水基团，HEA在成核过程中，也扮演着关键的角色。NaSS对高固含量 无皂乳液的聚合稳定性有很大影响；从透射电镜照片中，可以看出不同 NaSS用量时乳胶粒子的形态情况。此外还讨论了助溶剂对乳胶粒子形态 的影响、搅拌速率对聚合稳定性的影响以及保温时间与转化率之间的关系 等。 在制备出的高固含量无皂乳液的基础上，初步研究了其作为防水涂料 的应用。讨论了防冻剂、流平剂等助剂对涂料稳定性和防水膜层性能的影 响。特别的，提出了防水涂层的干湿循环老化实验，测试和比较了防水涂 层经过300次干湿循环后的断裂伸长率，发现防水涂层经过干湿循环老化 实验过后，断裂伸长率都有所下降。 关键词：多元共聚 高固含无皂乳液 防水涂料 干湿循环老化 J，reparation J，reparation of high·solid co—poIymer emulsiner-free latexes and studies Of the appIication as water—resistant coating Abstract With the studies of co(HEA／St／BA)emulsjfier-free polyme“zation，stable latexes of 50％solid content without emu】si囊er were suecessf．ully obtained，In the system，HEA not only o“钉s hydrophiIic group for the Iatex particlesbut also play an important role in the process of forming core，NaSS has an effect on the stability of polymerizatiOn of emulsmer-free latexes，and through the TEM photos， it wiU be found that various content of NaSS can Iead to dif代rent shapes of latex particles．In addition，the cosolvent’s effect on the shapes of latexes，the agitation rate’s eff色ct on the stability of polyme“zation of emulsi行er—free latexes，and the relation of tenlperature-keeping time and monomer conversion were also discussed． 0n the base of the preparation of high—s01id co·p01ymer emulsifier—fiee latexes， as water-resistant coating， the appllcation was studied． Such as antifreeze’s ef诧ct on the stability of coating and Ieveling agent’s effect on the capabilities of water-resistant film were primarily studied． EspecialIy， dry—wet—cycling agjng methOd was introduced， The tensibiljty of wate卜resistant film will decrease after 300 cycle． Key words： co-polymerization，high—solid emulsifier—flee 1atexes water—resistant coating，dry-wet-cyclin套aging 插图清单图1．1 插图清单 图1．1 乳液聚合时间．转化率曲线示意图 一 图1．2 微乳液的结构和类型 图1．3 微乳液类型转变示意图 · 图2．1 HEA用量对单体转化率曲线 图2．2 乳胶粒子稳定原理示意图 一 图2．3 聚合物的红外光谱图