高聚物氧化锆有机无机杂化材料的制备和表征-材料学专业论文.docxVIP

高聚物氧化锆有机无机杂化材料的制备和表征摘 高聚物氧化锆有机无机杂化材料的制备和表征 摘 要 本文以无机盐氧氯化锆为前驱物，制备氧化锆溶胶；然后分别与聚乙烯醇 (PVA)、聚乙烯醇缩丁醛(PVB)反应，制成PVA／zr02、PVB／zr02有机一无 机杂化高分子材料。 在氧化锆溶胶的制备当中，研究了H202的作用机理以及双氧水加入量、 加热方式等对溶胶稳定性的影响，确定了最佳的工艺条件。 在PvB／zr02杂化材料的制备中，运用IR技术、xRD、TGA等手段对此杂 化材料进行评价，讨论了溶胶分数的影响因素，发现Sol／PVB比值、双氧水加 入量以及后处理温度都会影响材料的溶胶分数。通过吸光度实验研究了反应过 程中无机粒子的大小和生长速率的影响因素，发现分次加水、控制温度都会减 小并稳定最终无机粒子的粒径。 在PvA，zr02杂化材料的制备中，同样运用IR技术、xRD、TGA等手段对 此杂化材料进行评价，并讨论了有机无机组分配比不同的杂化材料，其耐溶剂 性能的优劣。 将纯PVA、PVA／zr02杂化材料、纯PVB、PVB／zr02杂化材料制成的纺丝 液电纺成纤维，运用扫描电镜进行分析。讨论了有机无机组分配比以及金属盐 对杂化电纺纤维的影响，结果表明PVA／zr02=1：3．5(w／w)、PvB／zr02=4：1(物 质的量比)时，纤维光滑，分散比较均匀。随着二氧化锆含量的增加，纤维直径 变细，纺锤形珠节结构增多。加入金属盐NaCl后，纤维直径变细，圆形珠节 增多。 关键词：溶胶一凝胶法，有机无机杂化，聚乙烯醇，聚乙烯醇缩丁醛，氧化锆 The The preparation and characterization of polymer，zirconia hyb rid materials Abstract In thjs paper， inorganic salt(zirconia chIoride octahydrate) was used as precursor to prepare zirconia sol， then the s01 was reacted with poly(vinyI alcoh01)(PVA)and poly(vinyl butyral)(PVB)to prepare PVA／zf02、PVB／zr02 organic-inorganic hybrid materials． I“preparation of zirconia sol，the reaction mechanism of H202 and the infIuences of dosage of H202、the manner of calefaction on stability of sol were researched．And then the perfect technological condition was established． In preparation of PVB／Zr02 hybrid material，the characteriz州on techniques such as IR、XRD、TGA etc were used to evaluate the hvbrid material_lt was found that the ratio of sol／PVB、the dosage ofH202、the heat treatment temperature would innuence sol fhction in the mate“aI．By absorbency experiments，the influence factors of size and growing speed of inorganic particles were researched，it was found that adding water step by step and controlling temperature wouId reduce and stab订ize the diameter of inor2anic pa“cles． In preparation of PⅥVZr02 hybr．d material，such characterization techniques as IR、XRD、TGA etc were also used to evaluate the hvbrid material．The influence of the ratio of organic and inorganic components on the solvent resistance performance wa