高级管线钢LF炉精炼深脱硫的工艺研究-钢铁冶金专业论文.docxVIP

东北大学硕士学位论文 摘要 高级管线钢LF炉精炼深脱硫的工艺研究 摘 要 为提高钢铁产品的市场竞争力，第二炼钢厂根据鞍钢新钢铁公司对低硫钢的 生产要求，开发了用180tLF炉进行超低硫钢生产的技术，现已能够批量生产 【S]≤20x10’6的超低硫钢，为鞍钢新品种的开发、产品质量和经济效益的提高发挥 了重要作用。 研究结果表明，超低硫钢在转炉冶炼时首先要采用低硫原材料；成品平均 【S]=15xlO6，最低【s]为9xlO。6，脱硫渣操作工艺参数有待进一步优化。 钢包顶渣改质对于LF炉精炼脱硫影响较大，首先应从设备控制出钢下渣量 尽可能少，其次应通过顶渣改质将转炉氧化渣改质成还原脱硫渣系。 脱硫时LF炉渣中MnO较高，使炉渣氧化性过强，应改进脱氧制度以消除渣 氧势过高的不利因素。LF炉脱硫渣系应降低∑(FeO+Fe203+MnO)到1％以下， 脱硫结束时碱度大于4．0。 钢液增氮主要发生在从炉后到RH处理前这段时间，可采取控制钢包内密封 良好、优化吹心制度及采用顶吹心保护等措施减少该时间段内的钢液吸氮量。 考察了喂Ca．si合金线的处理效果，当前的喂线主要作用在于球化夹杂。喂 Ca-Si线能使A1203棱角状夹杂和硫化物夹杂全部变性，形成球状夹杂。 在目前钢水条件下，对于X60管线钢喂Ca-Si线500m即可达到夹杂物球化 的目的；对于X65管线钢喂Ca-Si线500m也可达到夹杂物球化的目的。 关键词：高级管线钢；LF炉；精炼：脱硫；喂线；夹杂物 JI  东北大学硕士学位论文 Abst ract Technical Study on the Deep Desulfurization of High-level Pipeline Steel Abstract In order to improve the competitive ability of steel production in market，the No．2 steel factory has developed the technology of producing ultra low—sulfur steel wim 1 80t LF according to the requirement of Angang New Steel Company Limited(ANSC)．The technology has already been put to use to produce ultra low—sulfur steel，which makes great contribution to the development of new kind of steel，the improvement of production quality and economical benefit for ANSC． The result shOWS that raw materials for ultra low—sulfur steel should contain low sulfur in BOF；the sulfur content of production is[S]=1 5 x 1 0。 on average，with a minimum of[S】=9×10～．The technological parameter of desulphurization slag in the process still needs optimizing． The addition agent for upper slag has a great effect on the refinement in LF．Firstly the quantity of lower slag should be control with the equipment when tapping off．Secondly，the addition should be used to change the BOF oxidizing slag into reducing slag． The content of MgO in slag is higher in the LF，as a result，the oxidizing ability of slag is too strong．So the deoxidization operation should be improved to eliminate oxygen and avoid the disadvantage ofhigh oxygen posi