dy等金属元素掺杂钛酸锂(li4ti5o2)的制备及其电化学性能的研究-物理化学专业毕业论文.docxVIP

放电测试等分析手段对锂铁氧化物结构及电化学性能进行研究。电化学测试结果表明， 放电测试等分析手段对锂铁氧化物结构及电化学性能进行研究。电化学测试结果表明， 当Fe和Ti的原子比为8：1时材料具有最好的电化学性能，100mA91电流密度下首次放 电比容量可达760．7 mAhg。1循环20圈容量仍能保持在55．0％。 关键词：锂离子电池钛酸锂掺杂锂铁氧化物 万方数据 AbstractWith Abstract With the continuous innovation of modern science and technology,people’S requirement of safety performance of lithium ion battery is higher and hi曲er,the traditional commercial lithium ion batteries are mostly do the cathode of carbon mat erials，but low carbon negative electrode potential close to lithium metal，SO large current charging conditions on the surface of carbon anode materials are easy to generate”dendritic”，causing security problems．This paper studied on the preparation and the method to improve properties of anode materials Li4TisOl2．The structure of the Li4Ti5012 material was investigated by X—ray diffraction (XRD)，Fourier transform infrared spectroscopy(FTIR)，scanning electron microscope(SEM)， and the electrochemical performance was mainly studied by using cyclic voltammetry(cv)， electrochemical impedance spectroscopy(EIS)and charge-discharge tests． The main experiments as follows： 1．A s01．gel method assisted hi曲temperature solid state reaction has been successfully employed to synthesize spinel Li4Ti5012 anode materials．In this work，the effect of Li：Ti atomic ratio Was systematically investigated．The structure of the Li4TisOl2 material Was investigated by X-ray diffraction(XRD)，scanning electron microscope(SEM)，and the electrochemical performance Was mainly studied by using cyclic voltammetry(CV)， electrochemical impedance spectroscopy(EIS) and charge—discharge tests． Results of electrochemical measurements demonstrated that when the atomic ratio of Li to Ti was 0．8：1． the best electrochemical performance was exhibited by the composite，delivering an initial discharge capacity of 1 60 mAh g-1 at 0．2 C and maintaining 78．1％of its initial capacity after 20 cycles． 2．For the first time，Dy(Dysprosium)一doped lithium titanate was prepared by a sol·gel me