emimdeph2o及其基液的纳米流体传递性质的研究.docx

优秀毕业论文 精品参考文献资料 [ZMrM][DEP]／ [ZMrM][DEP]／H20及其为基液的纳米流体传递性质的研究 Research on Transfer Properties of[EMIM][DEP]／H20 and Ionic Liquid—based Nanofluids Abstract Absorption heat pump(AHP)driven with industrial waste heat is a kind of energy-saving device．Conventional working pairs are”H20-LiBr”and”NH3-H20”．However． ”H20．LiBr”crystallizes easily in some conditions and has corrosive tendency to iron steel devices．”NH3-H20”has the toxicity and explosiveness．Consequently，many researches about new working fluids have been carried out to overcome these shortcomings in recent years． Ionic liquids(ILs)receive attention because of their characteristies such as wide liquid temperature range，low vapor pressure，less volatile and good solubility for most organic and inorganic solvents．It iS suggested that some ILs such as 1．ethyl．3．methylimidazolium diethylphosphate([EMIM][DEP])have the possibilities to be new working fluids in AHP．So， it iS essential to research their transfer properties systematically by experimental method and molecular dynamics(MD)simulation． Ionic liquid[EMIMI[DEP]is investigated here based on the experimental researches by our group．In the part of experiments，[EMIM][DEP】Was firstly prepared and then nano．silver particles and single—walled carbon nanotubes(swCNTl were dispersed into [EMIM][DEP】(INF)and its aqueous solutions(SNF)．Thermal conductivities of INF and SNF with various mass fractions of nano．silver particles were measured by transient hot-wire method at 303．15．353．15 K．The enhancement ratio iS only about 1．03 when也e mass fraction iS 8％．Moreover．thermal conductivities of INF and SNF with various mass fractions of SWCNT were alSO measured．The enhancement on the thermal conductivity iS obvious and the enhancement ratio with the mass fraction of 2％is 1．30 approximately． In the part of simulation，density。thermal conductivity and viscosity of ionic liquid [EMIM][DEP】and its aqueous solution at various mole fractions of IL in the temperature range from 303．15