反应工程基础程易chpt11catalysiscatalyticreactors.pptxVIP

CH.1 Mole balances;主要参考书;3;4;5;The use of catalyst DOES NOT vary DG Keq values of the reaction concerned, it merely change the PACE of the process. e.g. CH4(g) + CO2(g) = 2CO(g) + 2H2(g) DG0373=151 kJ/mol (100 oC) DG0973 =-16 kJ/mol (700 oC) At 100oC, DG0373=151 kJ/mol 0, the reaction won’t proceed with or without a catalyst At 700oC, DG0973=-16 kJ/mol 0, without a proper catalyst heating the mixture in reactor results no conversion of CH4 and CO2 at all; When Pt/ZrO2 or Ni/Al2O3 is present in the reactor at the same temperature, equilibrium conversion can be achieved.;7;8;9;Classification: Homogeneous vs. Heterogeneous Catalysis;11;12;13;14;15;16;Physical Adsorption Vs. Chemisorption;18;19;20;21;10.2 Steps in a catalytic reactions;23;24;25;26;27;28;29;30;31;Dissociated adsorption;33;;Multi-component adsorption isotherm;10.2.4 Surface reaction;37;38;39;Eley-Rideal vs LH Mechanism;41;42;Langmuir-Hinshelwood approach;Langmuir - Hinshelwood Kinetics;45;Surface-limited reaction;47;48;;50;51;52;53;54;55;56;10.3.5 Reforming Catalysts;n-pentene ? i-penteneSurface reaction is rate limiting step.;59;60;61;62;63;64;65;66;67;For surface-reaction-limited mechanisms;69;70;10.5 Chemical Vapor deposition (CVD);Microelectronic fabrication steps (cont’d);Bell-jar reactor (Siemens technology);Chemical Vapor Deposition;Rate law;76;改良西门子法制备多晶硅;多晶硅生产流化床工艺;10.6 Model Discrimination;80;81;82;Deactivation by Poisoning;84;85;Summary;Assuming that mass transfer is not rare-limiting, the rate of adsorption is The rate of surface reaction is The rate of desorption is At steady state, The total concentration of sires is ;If we assume that the surface reaction is rate-limiting, we set Chemical vapor deposition ;Catalyst deactivation. The catalyst activity is defined as: The rate of reaction at any time t is The rate of catalyst decay is For first-order decay: For second-order decay: 8. For slow catalyst decay the