水合肼净化烟气NOx过程的影响因素分析.PDF

30 5 V ol . 30 N o. 5 2009 10 ENER GY T ECH N OL OGY Oct . 2009 NOx 1 1 2 , , ( 1. 同济大学 热能与环境工程研究所, 上海200092; 2. 宝钢研究院, 上海201900) : 采用反应动力学和计算流体力学软 对水合肼还原高温烟气中N Ox 过程进行了模拟 2 4 计算根据模拟结果分析了烟气温度N H / N O 摩尔比烟气中氧含量停留时间烟气中N O 初 始浓度以及水合肼溶液的浓度对N O 净化效率的影响分析结果发现: N2 H 4 / N O 摩尔比取0 . 8, 使用质量分数为5% 浓度的水合肼溶液喷加到1023K 的烟气中并且保证停留时间尽量长, 可以取 得最好的N O 净化效果分析结果可以为实际操作提供指导 : 水合肼; N Ox ; 烟气净化; 反应动力学计算 : X201. 7 : A : 2009) Modeling Analysis of the DeNOx Process with Hydrazine Hydrate 1 1 2 HAN Suqiang , CHEN Dezhen , L Xianwei ( 1. Institut e o T hermal and Env ir onmental Eng ineering , T o ngji U niver sity, Shanghai 200092, China; 2. Baosteel T echnolog y Cent re, Shanghai 201900, China) Abstract: A reactio n kinetics model code and computational luid dy namics code has been employed to simulate the reductio n pr ocess o N Ox w ith hydrazine H ydrate in the lue gas . T he impact o di erent reaction condit ion such as lue g as temperature, N H / N O ratio, the O co ncentration , the r esidence time, initial N O concentr atio n and the 2 4 2 hy dr azine hydr ate so lutio n concentr atio n is investig ated. R esults show that 5% concentr ation o hydrazine hydr ate so lutio n inj ected in lue g as w here its temperature is 1 023 K , N H / N O rat