反应冷凝和蒸发模型及其在反应精馏中的应用-Core.PDF

38 10 Vol. 38 No. 10 2010 10 CHEM ICAL ENGINEER ING( CH INA ) O ct. 2010 叶建初, 郑艳梅, 沙 勇 ( , 361005) : , (TAME), 2, D a : ; ; ; : TQ 028 : A : 20 10) Reactive condensation and evaporation models and their application in reactive distillation process YE Jianchu, ZHENG Yanmei, SHA Yong ( College of Chem istr and Chem ical Engineering, X iam en Un iversit , X iamen 361005, Fujian Province, Ch ina) Abstract: In order to stud the coup ling betw een reaction and separation in the reactive distillation column, continuous reactive condensation and evaporation models w ere established. B means of themodels, the influence of differentD a numbers on the reactive d istillation process of tertiar am lmeth l ether ( TAME) w as investigated eitherw ith or w ithout inert components. As a resu lt, the rational configuration of column, the suitable range of reaction intensit , the excessive amoun t of methanol and the feasib le composition of products in th is reactive distillation process w ere obtained. K e words: reactive distillation; reactive condensation; reactive evaporation; reaction intensit , [ 67] [ 89] , , , , , , , , , [ 14] ,