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Proposal of a simple screening method for a rapid
preliminary evaluation of “heavy metals”
mobility in soils of contaminated sites
Valentina Pinto Francesca Chiusolo Carlo Cremisini
Received: 23 June 2009 / Accepted: 22 February 2010
# Springer-Verlag 2010
Abstract
Purpose Risks associated to “heavy metals” (HM) soi contamination depend not only on their total
content but, mostly, on their mobility. Many extraction procedures have been developed to evaluate HM mobility in contaminated soils, but they are generally time consuming (especially the sequential extraction procedures (SEPs)) and consequently applicable on a limited number of samples. For this reason, a simple screening method, applicable even “in field”, has been proposed in order to obtain a rapid evaluation of HM mobility in polluted soils, mainly focused on the fraction associated to Fe and Mn oxide/hydroxides。
对土壤中的重金属的污染的迁移性的初步快速的简单的筛选测定方法的建议
(摘要)
(对“重金属”在土壤中的污染风险联系不只局限于他们的总重量,通常来说,和他的迁移转化有关。在污染的土壤中很多萃取方法被又来评价重金属的迁移转化,但他们随着时间的而变特别是连续抽样,因此适用于有限数量的样本。由于这个原因,已提出建议,以获得一个快速的适用工作现场,甚至一个简单的筛选方法来重金属在土壤中的污染迁移转化,主要侧重于相关联的铁和锰的氢氧化物的分数。)
Materials and methods A buffer solution of trisodium citrate and hydroxylamine hydrochloride was used as extractant for a single-step leaching test. The choice of this buffered solution was strictly related to the possibility of directly determining, via titration with dithizone (DZ), the content of Zn, Cu, Pb and Cd, which are among the mostrepresentative contaminants in highly mineralised soils. Moreover, the extraction solution is similar, aside from for the pH value, which is the one used in the BCR SEP second step. The analysis of bivalents ions through DZ titration was exploited in order to further simplify and quicken the whole procedure. The proposed method generically measures, in few minutes, the concentration of total extractable “heavy metals” expressed as molL?1 without distinguishing between elements。
我们是用的材料和方法 A 缓冲溶液的钠枸橼酸和羟胺盐酸作为萃取剂一步浸出试验。此缓冲的解决方案的选择是密切相关的直接
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