活性氧化铝负载铁、钴催化过硫酸盐降解苋菜红的研究.PDFVIP

第39 卷第5 期 Vol.39 No.5 井冈山大学学报( 自然科学版) 2018 年9 月 September 2018 Journal of Jinggangshan University (Natural Science) 33 井冈山大学学报( 自然科学版) 33 文章编号：1674-8085(20 18)05-0033-05 活性氧化铝负载铁、钴催化过硫酸盐 降解苋菜红的研究 *徐清艳，黄晓东 （闽江学院海洋学院，福建，福州 350108 ） 摘 要：制备活性氧化铝负载铁、钴作为催化剂，并用XRD 和SEM 对该催化剂进行表征。考察了负载物初始浓 度配比，Na S O 浓度，催化剂用量，苋菜红初始浓度，紫外光光照时间，pH 值以及无机离子对降解苋菜红的影 2 2 8 响。实验结果表明：当催化剂中的Fe:Co = 1:2 时，其降解能力最强。在苋菜红初始浓度为40 mg/L 时，过硫酸钠 浓度为1.5 g/L ，催化剂用量为1.0 g/L ，pH 值为5，紫外光照射30 min 的条件下，苋菜红的脱色率最高可达97.91% 。 且不同无机离子对反应体系有一定的抑制作用。 关键词：活性氧化铝；负载铁、钴；活化；过硫酸钠；苋菜红 中图分类号：X52 文献标识码：A DOI: 10.3969/j.issn.1674-8085.20 18.05.007 DEGRADATION OF AMARANTH RED BY PERSULFATE WITH ACTIVATED ALUMINA LOADING FE-CO AS CATALYST * XU Qing-yan, HUANG Xiao-dong (Ocean College, Minj iang University, Fuzhou, Fuj ian 350108, China) Abstract: Activated alumina loaded with iron and cobalt was prepared as a catalyst. The catalyst was characterized by XRD and SEM . The effects of the factors such as the proportion of loaded substances, the concentration of sodium persulfate, catalyst dosage, initial concentration of amaranth red, the time of UV irradiation, pH value and different inorganic ions on the degradation of amaranth red were investigated. The results showed that when the ratio of Fe-Co in the catalyst was 1:2, the degradation ability was strongest. When the initial concentration of amaranth red was 40 mg/L, the initial concentration of sodium persulfate was 1.5 g/L, catalyst dosage was 1