柱前衍生-高效液相色谱-质谱联用法鉴定糖浆掺假蜂蜜-食品安全质量.PDF

8 2 Vol. 8 No. 2 2017 2 Journal of Food Safety and Quality Feb. , 2017 -- 1 2* 邱志超 , 官咏仪 (1. , 511447; 2. , 510623) 摘 要: 目的 方法 , , , , , ESI-MS SIR 结果 2- (2-AB) 2 --N-(2-PB) (DP1)(DP2)(DP3), (DP4) (DP5)(DP6)结论 , , 关键词: ; ; ; - Identification of adulterated honey by precolumn derivatization-high performance liquid chromatography-tandem mass spectrometry 1 2* QIU Zhi-Chao , GUAN Yong-Yi (1. Guangzhou Quality Supervision and Testing Institute, Guangzhou 511447, China; 2. Inspection and Quarantine Technology Center, Guangdong Entry-Exit Inspection and Quarantine Bureau, Guangzhou 510623, China) ABSTRACT: Objective To establish a method for the determination of adulterated honey. Methods Honey samples were dissolved and treated by vacuum drying, and then they were fluorescent labeled before separated by high performance liquid chromatography (HPLC) using NH2 column with acetonitrile and ammonium formate as mobile phase, and qualitatively analyzed by ESI-MS under SIR mode. Results It was shown that the fluorescent