慈溪市大气中PM10与其中水溶性离子污染特征研究.docVIP

PAGE １４ Ⅰ- PAGE 17 慈溪市大气中PM10与其中水溶性离子污染特征研究 摘 要：本文研究了慈溪市大气中PM10及其水溶性离子的分布特征。本实验通过对慈溪市四个季度的PM10监测，采用重量法与离子色谱法对样品进行分析，获得其年间浓度水平变化，了解其时空分布及相关性。对实验数据分析得知，PM10及其水溶性离子浓度与气压、气温有关。含量最高的水溶性离子是NH4+离子，浓度范围在0.01~10.85μg/m3；其次是NO3-，浓度范围在0.14~7.78μg/m3；再次是SO42-，浓度范围在0.05~6.62μg/m3；最低的Cl-的浓度范围在0.02~1.82μg/m3。SO42-、NO3-、Cl-的浓度市区高于乡镇。NH4+的浓度乡镇高于市区。水溶性离子的浓度整体冬季浓度高于夏季。污染主要来源于汽车尾气与工业燃煤。 关键词：PM10，水溶性离子，浓度水平，时空分布 The?research?on pollution patterns?of?PM10?and its water-soluble ions in?the atmosphere of Cixi, China? Abstract: We analyzed the pollution patterns of PM10 and its water-soluble ions in the atmosphere of Cixi, China. In this experiment, we monitored PM10 between four seasons of Cixi to analyze samples, obtain its concentration variation and understand the distribution and correlation of their spatial and temporal by using the gravimetric method and ion chromatography samples. Given the analysis of the experimental data we know that PM10 and water-soluble ions concentration are related to atmospheric pressure and air temperature. The highest content of water-soluble ions is NH4+, it’s concentration range is 0.01-10.85μg/m3; followed by NO3-, concentration range is 0.14-7.78μg/m3; SO42- concentration range is 0.05-6.62μg/m3; the lowest concentration is Cl- , whose concentration range is 0.02-1.82μg/m3. All of the concentration of SO42-, NO3- and Cl- are higher than the concentration of urban townships. The villages’ concentration of NH4+ is higher than the urban. Overall, the concentration of water-soluble ions in winter is higher than in summer. Pollution mainly comes from vehicle exhaust and industrial coal. Keywords: PM10, water-soluble ions, concentration level, temporal and spatial distribution 目录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc387860136 1引言 PAGEREF _Toc387860136 \h 4 HYPERLINK \l _Toc387860137 1.1研究的背景和意义 PAGEREF _Toc387860137 \h 4 HYPERLINK \l _Toc387860138 1.2现状研究和分析 PAGEREF _Toc387860138 \h 4 HYPERLINK \l _Toc387