等离子体改性纳米SnO2纤维丝吸附有机废气性能研究.docVIP

PAGE 等离子体改性纳米SnO2纤维丝吸附有机废气性能研究 摘 要：本文针对低温放电等离子体催化耦合技术降解有机废气过程中催化剂的吸附性能对降解过程的影响，研制了一种多孔的氧化物催化剂体系。亦即，采用介质阻挡放电（DBD）对静电纺丝法制备的SnO2纳米纤维催化剂进行了处理，研究了氧等离子体处理过程参数对催化剂结构、形貌和吸附性能的影响。研究结果表明，经过氧等离子体处理过后，SnO2纳米纤维表面出现许多垂直于纤维轴的纳米孔，从而提高了SnO2纳米纤维材料的比表面积，同时也提高了纳米SnO2纤维的吸附甲苯的活性。通过研究不同放电时间和放电功率等改性条件对SnO2纳米纤维的比表面积、孔径和甲苯的饱和吸附量的影响，确定了最佳的氧气等离子体改性条件。本研究表明，采用氧等离子体改性处理氧化物催化材料，是提高其有机物吸附、增大其表面积最有效和简单的方法之一。 关键词：气体放电改性；二氧化锡；氧等离子体；吸附；有机废气 Adsorption of volatile organic compounds on SnO2 nanofibers modified by plasma Abstract: In this paper，a porous oxide was developed as for the importance of adsorption properties of catalysts during removal process of organic exhaust gas by low temperature plasma catalytic coupling technique. That is, electrospun SnO2 nanofibers were modified by dielectric barrier discharge (DBD), and the effect of oxygen plasma treatment process parameters on the catalyst structure, morphology and adsorption properties were explored. The results show that, after oxygen plasma treatment, many nanopores perpendicular to the fiber axis SnO2 nano fiber surface were formed, thus improving the specific surface area of SnO2 nano fiber material, but also improving the adsorption activity of nano SnO2 fibers. Through the study of influence of different modification conditions, such as discharge time and discharge power on specific surface area, pore size and organic waste gas adsorption capacity of SnO2 nanofibers, the optimum oxygen plasma modification parameters were confirmed. This study shows that, the oxygen plasma modification to catalytic oxide materials is one of the most effective and simple methods to improve the adsorption of organic compounds and larger surface area. Keywords: gas discharge modification; Tin oxide SnO2; oxygen plasma; adsorption; organic waste gas 正文目录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc388170462 1引言 I- PAGEREF _Toc388170462 \h 1 HYPERLINK \l _Toc388170463 1.1研究背景 I- PAGEREF _Toc388170463 \h 1 HYPERLIN