静电纺CeO2纳米纤维的制备及催化氧化柴油机尾气PM的研究.docVIP

PAGE 静电纺CeO2纳米纤维的制备及催化氧化 柴油机尾气PM的研究 摘 要：本文研究了采用静电纺丝技术制备PVP/Ce(NO3)3 复合纳米纤维的最佳条件，并同时成功制备了PVP/ Ce(NO3)3/AgNO3和PVP/ Ce(NO3)3/AgNO3/Pr(NO3)3 复合纳米纤维。考察了焙烧温度及助剂的添加对CeO2纤维催化材料的结构及性能的影响。将所制备的复合纳米纤维分别在500 ℃和800 ℃下焙烧4 h，获得了相对应的氧化物纳米纤维催化剂。并采用TGA、XRD、BET和SEM等分析手段对纤维催化剂进行了表征。结果表明，制备的催化剂均有很好的活性，而且Ag掺杂的CeO2-Ag纳米纤维催化剂催化活性有很大提高，而Pr的掺杂则使得纳米纤维催化剂的热稳定性和抗烧结能力得到较大程度地加强。XRD和BET的表征结果也证明了Pr的掺杂有利于提高纳米纤维催化剂的抗烧结性能。 关键词：静电纺；纳米纤维；催化氧化；柴油机尾气；PM CeO2 nanofibers fabricated via electrospinning and their catalytic performance for diesel PM oxidation Abstract: The best parameters for the preparation of PVP/Ce(NO3)3 composite nanofibers via electrospinning technology have been investigated in this study. PVP/Ce(NO3)3/AgNO3 and PVP/Ce(NO3)3/AgNO3/Pr(NO3)3 composite nanofibers were also successfully prepared. In addition, the effect of calcination temperatures and doping of metals on the structure and performance of CeO2 fibers has also been explored. After being calcined at 500 ℃ and 800 ℃ for 4 h, respectively, these composite nanofibers became oxide nanofiobers catalysts. Then, the samples were characterized by means of TGA、XRD、BET and SEM. The results indicated that the catalytic activity of these CeO2 nanofibers was high. And the catalytic activity of the Ag-doped CeO2 nanofibers was improved significantly. The doping of Pr increased the thermal stability and the sintering resistance of nanofiber catalysts to a large extent, which coincided with the results of XRD and BET. Keywords: electrospinning; nanofibers; catalytic oxidation; diesel PM 正文目录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc387936543 1引言 I- PAGEREF _Toc387936543 \h 1 HYPERLINK \l _Toc387936544 1.1 研究的背景与意义 I- PAGEREF _Toc387936544 \h 1 HYPERLINK \l _Toc387936545 1.2 研究现状 I- PAGEREF _Toc387936545 \h 2 HYPERLINK \l _Toc387936546 1.2.1 纳米纤维催化材料的制备方法 I- PAGEREF _Toc387936546 \h 2 HYPERLINK \l _Toc387936547 1.2.2 静电纺丝技术 I- PAGEREF _Toc387936547 \h 2 HYPERLINK \l _Toc387936548 1.3 研究基本思路与内容 I- PAGEREF _Toc387936548 \h