污染物自组装提高电化学降解2-氟苯胺的性能.docVIP

- PAGE 11 - 污染物自组装提高电化学降解2-氟苯胺的性能 摘要：污染物自组装是一种通过某种驱动力使污染物自发改性到电极表面，进而同步加速自身降解的过程。针对有机氟化物碳氟健稳定、有机氟废水毒性大、难降解等问题，通过投加自组装辅助药剂（NO2-），考察典型有机氟化物2-FA的去除性能、碳系电极改性特征以及污染物降解途径，并分析了污染物自组装去污机理。结果表明，通过添加0.5mM亚硝氮的NN反应器，可提高2-FA去除速率105.7%，脱氟率203.0%，反应5h后的电极表面覆盖大量红色杆状物质。CA（计时安培法）和CV（循环伏安法）结果表明改性物质能提高电极界面电子传递效率。通过氮平衡计算有42.4%的氮素转化为氮气，且出水NO2-降至2mg/L以下，表明电极表面可能发生重氮盐改性。NN电极表面物质主要为苯环，液相主要产物为氟苯酚。电流趋势、CV及SEM结果表明改性物质在电极表面发生不可逆氧还原反应。针对实际废水水质复杂的问题，得出最佳污染物自组装条件为pH5-7，电压2V，同时发现低盐度、COD对自改性过程的影响不显著。污染物自组装是一种具有巨大应用潜力的废水处理新技术。 关键字：自组装；电化学；石墨电极；2-FA ；NO2- Enhanced removal of 2–Fluoroanline by pollutants self-assembly in electrochemical system Abstract: Self-assembled in solution refers to the adsorption on the electrode substrate through spontaneous chemical bond, and then improve removal of pollutants itself. In this study, the 2-FA degradation performance, electrodes surface characterization, HYPERLINK javascript:void(0);electrochemical?properties and degradation pathway were surveyed. This study found the 2-FA removal rate in NN increased 105.7% and the defluorination rate of 2-FA increased 203.0% compared with CK. The electrode covered a large number of rod-like substances. The current profile showed that the current increasing at the initial stage and the CV showed the rod-like substance on the electrode could improve the electron transfer rate between solid-liquid interfaces. 42.4% nitrogen disappeared and most turn into nitrogen in the reactor NN and the residual NO2- of NN less than 2mg/L which is low effect to the environment. Those results indicated electrode surface functionalization by reduction of aryl diazonium salts. The main product is fluorophenol and benzene ring which is easier to degradation. The optimum reaction pH is 5-7, the best voltage of 2V. Salinity and COD have no effect on the self-assembly process. Therefore, this electrical method combined nitrite nitrogen, is very promising for the treatment of wastewater containing fluoroaniline compounds. Keywords: Self-assembled;