《磷酸酯功能单体共聚改性水溶性树脂的合成及防腐性能的研究》-毕业论文设计（学术）.docVIP

PAGE l 本科毕业设计（论文） 磷酸酯功能单体共聚改性水溶性树脂的合成及防腐性能的研究 学 院 轻工化工学院 专 业 化学工程与工艺 （精细化工方向) 摘要 近年来，随着国家对VOCs排放物要求的限制，水性涂料得到了快速的发展，加上金属腐蚀问题的加剧，水性防腐涂料也应运而生。水溶性丙烯酸树脂由于具有良好的光泽度、耐候性、耐化学性和储存稳定性以及无污染、无毒性、无刺激性和生产安全、价格便宜等优点而作为一种新型的水性涂料用成膜基料。但常规丙烯酸树脂存在如成膜温度高、膜硬度低、抗粘性差、耐水性不好、附着力差等缺点。因此，合成能克服以上缺陷的新型水性丙烯酸树脂己成为当前的研究热点之一。 本文主要采用溶液聚合法合成了水溶性丙烯酸树脂，讨论了不同溶剂、引发剂以及单体等因素对丙烯酸树脂的影响；然后采用具有高活性的磷酸酯功能单体(PAM-100)进行共聚改性，并通过红外分析仪(IR)、漆膜附着力实验仪、漆膜铅笔划痕硬度计、漆膜冲击器、电化学分析仪、数字旋转粘度计等实验仪器进行结构的表征与树脂的相关性能测试，对改性丙烯酸树脂的结构与性能进行了系统地分析与研究。最终确定了较佳的配比：混合溶剂（正丁醇：乙二醇单丁醚=4：1，质量比）；引发剂BPO占树脂的2.5％，分子调节剂十二硫醇占树脂的1%；单体配比（甲基丙烯酸：丙烯酸丁酯：苯乙烯：甲基丙烯酸甲酯：丙烯酸羟丙酯=6%：27.5%：15%：27.5%：20%，质量比）；PAM-100占树脂的4%，所合成的改性水溶性丙烯酸树脂固含量最高可达65%，且具有较强的耐水性以及耐腐蚀性。 关键词：水溶性丙烯酸树脂，磷酸酯功能单体PAM-100，溶液聚合，防腐 注：本设计（论文）题目来源于教师的企业科研项目。 Abstract In recent years, the development of water-based coatings is rapid with the increasing demand for VOCs emissions control in our country. The water-based anti-erosion paint came into being as the serious problem of metal corrosion. The water-soluble acrylic resin have the advantages such as good glossiness, weather-resistant, chemical resistance and storage stabilization and non-contamination, non-toxicity, non-skin irritation, and price and safety of production. Therefore,it become the new water-based paint. But it also has some disadvantages, such as high film forming temperature, low hardness, poor anti-after tack, poor water-resistant, low adhesion, etc. So the high performance water-soluble acrylic resin which can overcome those disadvantages becomes research hotspot at present. This paper mainly describes the synthesis of water-soluble acrylic polymer resin by solution polymerization and investigate the impact of different solvents, initiator, and monomers on the acrylic; then discribes the copolymerization of water-soluble acrylic resin using phosphate functional monomer which is high activity. The structure and properties of modified acrylic resin is analyzed and studied systemically by infrared analyzer