保健食品中邻苯二甲酸二异辛酯快速筛查的定性定量分析方法.PDF

4 5 Vol. 4 No. 5 2013 10 Journal of Food Safety and Quality Oct. , 2013 * 朱小红 , 陈 蓓, 朱建荣, 林 芳, 刘海静 (, 710065) 摘 要: 目的 (diisooctyl phthalate, DEHP) 方法 , -结 果 DEHP 0.01070~10.70 μg/mL , 0.9987, (LOD) 0.02 μg/g, (LOQ)0.07 μg/g73.8%~96.8%; 结论 , , DEHP 关键词: ; -; ; ; The method of rapid screening, qualitative and quantitative analysis for diisooctyl phthalat in health food * ZHU Xiao-Hong , CHEN Bei, ZHU Jian-Rong, LIN Fang, LIU Hai-Jing (Shaanxi Institute for Food and Drug Control, Xi’an 710065, China) ABSTRACT: Objective To develop a gas chromatograph-mass spectrometry method for rapid screening, qualitative and quantitative analysis of diisooctyl phthalat in health food. Methods Samples were ultrasoni- cally extracted by ethanol and analyzed by LC-MS/MS. Mass data acquisition was conducted under selected ion scan mode. Results The method showed a good linearity in the range of 0.01070~10.70 μg/mL (r0.9987) for diisooctyl phthalats. The limit of detection of this method was 0.02 μg/g (S/N=3). The limit of quantitative of this method was 0.07 μg/g (S/N=10). The recoveries were 73.8%~96.8%. Conclusion This method is con- venient, fast, accurate, reliable to operate, and it is suitable for the determination of diisooctyl phthalat in health food. KEY WORDS: diisooctyl phthalate; gas chromatography-mass spectrometry (GC-MS); fast screening method;