Pd负载碳纳米球催化SuzukiMiyaura偶联反应.docVIP

河北农业大学理学学士毕业论文 1 Pd负载碳纳米球催化Suzuki-Miyaura偶联反应 化学1301解畅 指导教师：王春 摘要：本文将钯负载到碳纳米球材料上，制得的该催化剂纳米球的尺寸均一，金属粒子钯被介孔碳固定、尺寸小且分布均匀，易于分离，比表面积大，性质稳定，易于回收且可以在温和的条件下催化Suzuki-Miyaura交叉偶联反应。回收的催化剂被重复使用五次催化活性无显著的降低。 关键词：碳纳米球；钯；Suzuki-Miyaura偶联反应 Carbon nanospheres with well-controlled nano-morphologies as support for Pd catalyzed Suzuki coupling reaction Abstract: Suzuki coupling reaction of palladium catalyst is one of the effective methods of construction of carbon-carbon bonds, it’s also one of the importance of carbon-carbon bonds coupling reaction. Uniform carbon nanospheres (UCS) with well-controlled nano-morphologies were fabricated by hydrothermal carbonization of sucrose in the presence of kayexalate. The highly dispersed and ultrafine Pd nanoparticles were successfully encapsulated in UCS by a facile approach. This article mainly expounds the Pd@UCS charcoal carbon-carbon bonds catalyzed coupling reaction. The prepared Pd@UCS indicated efficient catalytic activity for the Suzuki-Miyaura coupling reactions at mild condition. And catalyst recycling and the reaction of catalytic efficiency. Moreover, the catalyst could be recycled by a facile approach. Keyword: biomass; uniform carbon nanospheres; Pd; Suzuki coupling reaction. 河北农业大学理学学士毕业论文 河北农业大学理学学士毕业论文 目录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc484095430 1.引言 PAGEREF _Toc484095430 \h 1 HYPERLINK \l _Toc484095431 2实验部分 PAGEREF _Toc484095431 \h 1 HYPERLINK \l _Toc484095432 2.1试剂与仪器 PAGEREF _Toc484095432 \h 2 HYPERLINK \l _Toc484095433 2.2碳纳米球的合成 PAGEREF _Toc484095433 \h 2 HYPERLINK \l _Toc484095434 2.3 Pd@UCS的合成 PAGEREF _Toc484095434 \h 2 HYPERLINK \l _Toc484095435 2.4 Suzuki-Miyaura反应的一般步骤 PAGEREF _Toc484095435 \h 3 HYPERLINK \l _Toc484095436 2.5回收循环利用的测试 PAGEREF _Toc484095436 \h 3 HYPERLINK \l _Toc484095437 3结果与讨论 PAGEREF _Toc484095437 \h 3 HYPERLINK \l _Toc484095438 3.1 样品的表征 PAGEREF _Toc484095438 \h 3 HYPERLINK \l _Toc484095439 3.2催化Suzuki-Miyaura 反应的研究 PAGEREF _Toc484095439 \h 5 HYPERLINK \l _Toc484095